Sökning: "Umpolung Strategy"
Hittade 2 avhandlingar innehållade orden Umpolung Strategy.
1. Multicomponent Catalytic Reactions : Theoretical and Experimental Studies
Sammanfattning : In this thesis, Density Functional Theory (DFT) methods have been applied to study the mechanisms of three different multicomponent organic reactions. Also, a new synthetic procedure for the preparation of quinolinium salts is presented, and its mechanism also studied by DFT calculations. LÄS MER
2. Catalytic Methods to Convert Allylic Substrates through Hydride and Proton Shifts : Transition Metal-Catalyzed and Organocatalyzed Approaches
Sammanfattning : The present thesis describes the development of new catalytic protocols to transform allylic substrates into a wide variety of versatile carbonyl and vinyl organic compounds. All procedures that are described in this work have in common the existence of one or more hydrogen shifts as key steps in the mechanism of the reactions. LÄS MER