Sökning: "Isotope"

Visar resultat 16 - 20 av 419 avhandlingar innehållade ordet Isotope.

  1. 16. Isotopes as Mechanism Spies : Nucleophilic Bimolecular Substitution and Monoamine Oxidase B Catalysed Amine Oxidation Probed with Heavy Atom Kinetic Isotope Effects

    Författare :Susanna MacMillar; Olle Matsson; Anita Hussénius; Daniel M. Quinn; Uppsala universitet; []
    Nyckelord :Organic chemistry; nucleophilic bimolecular substitution SN2; kinetic isotope effects; precision conductometry; monoamine oxidase B MAO B; reaction mechanism; carbon 11C 14C kinetic isotope effect; ion pairing triple-ion formation; para-substituted benzyl chlorides; tetrabytylammonium cyanide; Organisk kemi;

    Sammanfattning : This thesis concerns the study of reaction mechanisms by means of kinetic isotope effects (KIEs). Studies of the nucleophilic bimolecular substitution (SN2) reaction had the dual purpose of improving our fundamental understanding of molecular reactivity and assessing the ability of kinetic isotope effects to serve as mechanistic tools. LÄS MER

  2. 17. Isotope Ratio and Trace Element Measurements Using Inductively Coupled Plasma – Mass Spectrometry : Method Development and Applications in Environmental Forensics

    Författare :Simon Pontér; Anders Widerlund; Hjalmar Laudon; Luleå tekniska universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Isotope ratio measurements; screening analysis; ICP-MS; MC-ICP-MC; multi-tracer studies; fractionation; Environmental Forensics; Tracing; Tillämpad geokemi; Applied Geochemistry;

    Sammanfattning : Environmental Forensics is a scientific methodology developed for identifying sources, the timing of release, and transport pathways for potentially hazardous environmental contaminants. It combines a variety of analytical methods with principles derived from disciplines such as chemistry, geology, geochemistry, hydrogeology, and statistics, with the purpose to provide objective scientific and legal conclusions on the source and/or time of a contaminant release. LÄS MER

  3. 18. Instrumental and methodological developments for isotope dilution analysis of gaseous mercury species

    Författare :Tom Larsson; Erik Björn; Holger Hintelmann; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Mercury; gas; species; speciation analysis; isotope dilution analysis; permeation tubes; Analytical chemistry; Analytisk kemi;

    Sammanfattning : This thesis deals with instrumental and methodological developments for speciation analysis of gaseous mercury (Hg(g)), based on isotope dilution analysis (IDA). The studied species include Hg0, (CH3)2Hg, CH3HgX and HgX2 (where X symbolises a negatively charged counter ion in the form of a halide or hydroxyl ion). LÄS MER

  4. 19. Iron in the Lena River basin, NE Russia : Insights from microscopy, spectroscopy and isotope analysis

    Författare :Catherine Hirst; Carl-Magnus Mörth; Per Andersson; Mats Erik Åström; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; iron; reactivity; isotopes; permafrost; river; Arctic; Marine Geology; maringeologi;

    Sammanfattning : Iron is an important mediator of biotic and abiotic processes on the Earth’s surface, being an electron acceptor in organic matter degradation, a surface for organic matter and trace element adsorption, and a required element for enzymatic processes during primary production. Yet, the role of iron as a mediator of carbon and trace element cycling in high latitude, permafrost-dominated regions remains poorly investigated. LÄS MER

  5. 20. Mysid growth, stable isotope fractionation, and energetics : implications for food web studies

    Författare :Elena Gorokhova; Ora Johansson; Stockholms universitet; []
    Nyckelord :Systems Ecology; systemekologi;

    Sammanfattning : Field data, stable isotope analyses of the Baltic Sea food web structure,and experimental studies of the functional response indicate that theomnivorous crustacean Mysis mixta (Crustacea, Mysidacea) has no distinct trophic position, but can potentially affect plankton communitystructure and compete with herring and sprat for the zooplankton. Toevaluate field data on mysid body constituents, abundance and populationstructure, and that of their potentialprey, basic knowledge of feeding behaviour, growth mechanisms, andreproductive capabilities are required. LÄS MER