Sökning: "dynamic reversible systems"

Visar resultat 1 - 5 av 22 avhandlingar innehållade orden dynamic reversible systems.

  1. 1. Dynamic Systems : Enzymatic Synthesis, Exchange Reactions and Applications in Materials Science

    Författare :Yang Zhang; Olof Ramström; Mihail D. Barboiu; KTH; []
    Nyckelord :constitutional dynamic chemistry; reversible reactions; kinetic resolution; dynamic kinetic resolution; enzyme catalysis; lipase; asymmetric synthesis; racemization; oxazolidinone; organogel; enamine; nitroaldol reaction.;

    Sammanfattning : This thesis is divided into three parts, revolving around the developments of dynamic systems utilized in dynamic kinetic resolution (DKR) and constitutional dynamic chemistry (CDC).The first section gives an introduction to constitutional dynamics, the core concept of this thesis. LÄS MER

  3. 2. Discovery-Oriented Screening of Dynamic Systems: Combinatorial and Synthetic Applications

    Författare :Marcus Angelin; Olof Ramström; Stefan Kubik; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; chemical education; crystallization; dynamic combinatorial chemistry; dynamic combinatorial resolution; dynamic system; enzyme catalysis; isoindolinone; lipase; nitroalcohol; nitroaldol reaction; phthalide; reversible; secondary alcohol; systems chemistry; tandem reaction; Organic chemistry; Organisk kemi; Bioorganic chemistry; Bioorganisk kemi;

    Sammanfattning : This thesis is divided into six parts, all centered around the development of dynamic (i.e., reversibly interacting) systems of molecules and their applications in dynamic combinatorial chemistry (DCC) and organic synthesis. LÄS MER

  4. 3. An Empirical Study of the Global Behavior of Structured Overlay Networks as Complex Systems

    Författare :Ruma R. Paul; Vladimir Vlassov; Alberto Montresor; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Complex Computing Systems; Designing Complex Systems; Structured Overlay Networks; Hostility of Operating Environments of Computing Systems; Informations- och kommunikationsteknik; Information and Communication Technology;

    Sammanfattning : Distributed applications built on top of Structured Overlay Networks (SONs) operate based on certain self-* behaviors of the underlying Peer-to-Peer network. Among those, self-organization and self-healing are the two most prominent and assumed properties. LÄS MER

  5. 4. Responsive Molecular Systems through Dynamic Covalent Chemistry

    Författare :Antanas Karalius; Zoltan Szabo; Stefan Matile; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; stimuli-responsiveness; dynamic covalent reactions; systems chemistry; constitutional dynamics; non-equilibrium systems; nitroaldol reaction; dynamers; reversible polymerization; boronate ester; imine ligand; metal coordination; self–assembly; emergent properties; network topology.; stimuli-responsivitet; dynamiska kovalenta reaktioner; systemkemi; konstitutionell dynamik; icke-jämviktssystem; nitroaldolreaktion; dynamerer; reversibel polymerisation; boronester; iminligand; metallkoordination; själv-organisation; emergenta egenskaper; nätverkstopologi.; Kemi; Chemistry;

    Sammanfattning : Nature tends to inspire research in chemistry. Systems that emerge from molecules interacting via reaction networks is something that life has mastered over the course of evolution in order to produce complexity. Dynamic reactions are key in systems chemistry, where reaction networks give rise to complex, emergent behavior. LÄS MER

  7. 5. Chemoenzymatic Resolution in Dynamic Systems : Screening, Classification and Asymmetric Synthesis

    Författare :Yan Zhang; Olof Ramström; Sabine Flitsch; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; constitutional dynamic chemistry; dynamic systemic resolution; dynamic kinetic resolution; enzyme catalysis; transesterification; enzyme promiscuity; asymmetric synthesis; pattern recognition; self-inhibition.;

    Sammanfattning : This  thesis  is  divided  into  four  parts,  all  centered  around  Constitutional Dynamic  Chemistry  (CDC)  and  Dynamic  Kinetic  Resolution  (DKR)  using biocatalysts for selective transformations, and their applications in screening of bioactive compounds, organic synthesis, and enzyme classification.   In  part  one,  an  introduction  to  CDC  and  DKR  is  presented,  illustrating  the basic  concepts,  practical  considerations  and  potential  applications  of  such dynamic systems, thus providing the background information for the studies in the following chapters. LÄS MER