Sökning: "bio-inspired iron complexes"

Hittade 1 avhandling innehållade orden bio-inspired iron complexes.

  1. 1. Atom and Group Transfer Reactions Involving High-valent Iron Complexes

    Författare :Yong Li; Kemisk fysik; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Iron enzymes; high-valent iron intermediates; bio-inspired iron complexes; FeIV=O; FeIV=NR; catalytic reactions; electronic effects; steric restriction.;

    Sammanfattning : Iron enzymes play critical roles in biological oxidation reactions by utilizing highly reactive high-valent iron intermediates, such as FeIV=O, FeV(O)(OH), and FeIV=NR species, for catalytic reactions. These intermediates exhibit remarkable catalytic behavior with high reactivities and high regio- and stereospecificity in various biochemical reactions. LÄS MER