Sökning: "Resolubilization"

Hittade 2 avhandlingar innehållade ordet Resolubilization.

  1. 1. Surfactant Responsive Cross-Linked Polymer Hydrogels

    Författare :Jesper Sjöström; Research Policy Institute (RPI); []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Physical chemistry; Fysikalisk kemi; Two-step binding isotherms; Resolubilization; Nonmonotonic transient volume changes; Swelling isotherms; Divinyl sulfone DVS ; Polyquaternium; Cellulose ethers; Amphiphilic cross-linked polymers; Responsive gels; Polymer-surfactant interactions;

    Sammanfattning : The focus of the thesis is on chemically cross-linked hydrogels which drastically change their volume when immersed in solutions of different ionic surfactants (with or without added salt). The two main questions addressed are: (1) How useful are simple gel swelling experiments to the study of polymer-surfactant interactions?, and (2) How does the volume of a cross-linked polymer gel change when it is immersed in a surfactant solution, both with respect to the equilibrium swelling and with respect to transient volume changes? Most of the gels studied were prepared by cross-linking linear polymers, which were well studied derivatives of hydroxyethyl cellulose (HEC). LÄS MER

  2. 2. Molecular Exchange in Colloidal Dispersions

    Författare :Alex Evilevitch; Kemiska institutionen; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; charged micoremulsion droplets; kinetics; mechanism.; Physical chemistry; Fysikalisk kemi; molecular transport; cell model; infinite dilution limit; turbidity measurements; oil solubilization; computer simulation; modeling; monomer diffusion; molecular exchange; Microemulsion droplets; oil droplets;

    Sammanfattning : This thesis is a study of molecular exchange between the aggregates in a colloidal dispersion. The problem of oil molecular transport at resolubilization of big oil drops by smaller microemulsion droplets is considered as an experimental model system. LÄS MER