Sökning: "low-coordinate"

Hittade 3 avhandlingar innehållade ordet low-coordinate.

  1. 1. Low-Coordinate Organopnictogens : Synthesis and Optoelectronic properties

    Författare :Muhammad Anwar Shameem; Andreas Orthaber; Roland Christian Fischer; Uppsala universitet; []
    Nyckelord :Pnictogen; phosphorus; arsenic; phosphaalkenes; arsaalkenes; phospholes; arsoles; alkynes; π-conjugation; PAHs; Fullerene-C60; sumanene; truxene; organic electronics;

    Sammanfattning : This thesis work is based on the development of novel organopnictogen compounds and the exploration of their potential applications in organic electronics. In particular, incorporation of phosphorus and arsenic into π-conjugated systems is known to modify the optoelectronic properties. LÄS MER

  3. 2. Low-coordinate Organosilicon Chemistry : Fundamentals, Excursions Outside the Field, and Potential Applications

    Författare :Muhammad Rouf Alvi; Henrik Ottosson; Joji Ohshita; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; organosilicon; silene; silaaromatics; silenolate; hypersilyl group; alcohol protection; molecular switch; Kemi med inriktning mot organisk kemi; Chemistry with specialization in Organic Chemistry;

    Sammanfattning : This thesis reports on unsaturated silicon compounds, as well as excursions from these into germanium chemistry, single molecule electronics, and silyl protective group chemistry. Both experimental and computational investigations were performed. LÄS MER

  4. 3. Functional and Modular As=C and P=C Group Motifs

    Författare :Daniel Morales Salazar; Andreas Orthaber; Jose Goicoechea; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; materials; physical chemistry; arsaalkenes; phosphaalkenes; DBU; fluorene; photochemistry; arsenic; phosphorus; carbon; hydrogen; sulfur; gold; copper; organic materials; organic electronics; molecular electronics; polymers; transition metal complexes; molecular materials; small molecule; hydrogen bonding; electrochemistry; cyclic voltammetry; chronoamperometry; electropolymerization; artificial intelligence; potentiodynamic; modularity; functionality; XPS; DFT; π-conjugation effects; 2D-NMR; disilenes; siliconoids; group motifs; functional group; emergence; reactivity; reactive systems; organometallic complexes; π-delocalization; low-coordinate; main group chemistry; heavy p-block elements; pnictogens; copper I complex; gold I complex; photosensitizer; XRD; spectroelectrochemistry; electrochromism; smart materials; synthesis; phosphaalkene ligands; imine ligands; hysteresis-like criteria; representative settings; optimal criteria; transient covalence; interactive image; conformer; isomer; ligand scrambling; nanomaterials; stimuli-responsive; optical properties; ligand design; molecular design; X-ray crystallography; emission; self-assembly; As=C; Si=Si; P=C; multiple bond; equilibrium; heteroalkenes; alkenes; reversibility; Raman; ATR-FTIR; ERDA; Kemi; Chemistry;

    Sammanfattning : This work focuses on the design, synthesis, characterization, and application projections of low-coordinated heavy pnictogen-containing (described by the generic letter E, hence E=C) phosphaalkenes (P=C) and arsaalkenes (As=C), with emphasis on the E=C group motifs. The work aims to understand their functional and modular character, reactivity, and potential applications by stabilizing, isolating, and characterizing these species in low-coordination environments. LÄS MER