Sökning: "alkynes"

Visar resultat 1 - 5 av 21 avhandlingar innehållade ordet alkynes.

  1. 1. Oxidative Trifluoromethylation and other Functionalization Reactions of Alkenes and Alkynes

    Författare :Pär Janson; Kálmán Szabó; Antonio Togni; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; palladium; copper; transition metal; trifluoromethylation; catalysis; acetoxylation; difunctionalization; oxidation; mechanistic study; alkenes; alkynes; quinones; organisk kemi; Organic Chemistry;

    Sammanfattning : This thesis concerns the use of various potent oxidants in organic synthesis. The main focus is directed at selectively introducing trifluoromethyl groups into compounds containing double or triple bonds. All reactions proceed under mild conditions and can in most cases be performed on the bench-top. LÄS MER

  2. 2. Development of new Catalytic Methods for the Selective Synthesis of Heterocycles

    Författare :Stalin Reddy Pathi Pati; Nicklas Selander; Masaharu Nakamura; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; catalysis; indium; heterocycles; Lewis acid; multicomponent reactions; furans; alkynes; organisk kemi; Organic Chemistry;

    Sammanfattning : In the field of organic chemistry, the development of new catalytic methods for the synthesis of complex molecules from simple precursors is a top priority. The main focus of this thesis concerns the diastereoselective synthesis of heterocyclic compounds using main group elements as Lewis acid catalysts. LÄS MER

  3. 3. Low-Coordinate Organopnictogens : Synthesis and Optoelectronic properties

    Författare :Muhammad Anwar Shameem; Andreas Orthaber; Roland Christian Fischer; Uppsala universitet; []
    Nyckelord :Pnictogen; phosphorus; arsenic; phosphaalkenes; arsaalkenes; phospholes; arsoles; alkynes; π-conjugation; PAHs; Fullerene-C60; sumanene; truxene; organic electronics;

    Sammanfattning : This thesis work is based on the development of novel organopnictogen compounds and the exploration of their potential applications in organic electronics. In particular, incorporation of phosphorus and arsenic into π-conjugated systems is known to modify the optoelectronic properties. LÄS MER

  4. 4. Mechanistic Studies of Organocopper Chemistry by NMR Spectroscopy: Conjugate Additions to Alkynes and Alkenes

    Författare :Karolina Nilsson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; cyanocuprate; organocopper reagents; ynones; lithium dimethylcuprate; 13C and 15N NMR spectroscopy; pi-complexes; mechanism; enoates; 6Li; 1H-HOESY; ynoates; conjugate addition;

    Sammanfattning : This thesis focuses on the mechanisms of organocopper reactions, in particular the reactions with activated alkynes (ynoates and ynones). These reactions are of interest in the formation of new highly functionalized double bonds with control of the stereochemistry. LÄS MER

  5. 5. π-complexes of terminal alkynes and alkenes with copper(I) : synthesis and structural characterization

    Författare :Katarina Brantin; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; olefin; alkene; crystal structure; alkyne; synthesis; acetyne; infrared; pi-complex; copper I ;

    Sammanfattning : .... LÄS MER