Sökning: "Decarbonylation"

Hittade 4 avhandlingar innehållade ordet Decarbonylation.

  1. 1. Carbon Monoxide in Catalytic Hydrogenations: A Poison or a Promoter?

    Författare :Ulf Schröder; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : The hydrogenation of a,b-unsaturated aldehydes was studied over a platinum catalyst. It was shown that the catalyst was rapidly deactivated by CO formed by decarbonylation of the aldehyde. This deactivation was suppressed by the addition of small amounts of oxygen to the feed, since CO was oxidized to CO2 in the presence of oxygen. LÄS MER

  3. 2. Transition Metal Catalysis for Selective Synthesis and Sustainable Chemistry

    Författare :J. Johan Verendel; Pher G. Andersson; Reko Leino; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Catalysis; Transition metals; Asymmetric catalysis; Hydrogenation; Sustainable chemistry; Kemi med inriktning mot organisk kemi; Chemistry with specialization in Organic Chemistry;

    Sammanfattning : This thesis discusses the preparation and use of transition-metal catalysts for selective organic chemical reactions. Specifically, two different matters have been studied; the asymmetric hydrogenation of carbon-carbon double bonds using N,P-ligated iridium catalysts and the metal-catalyzed transfer of small molecules from biomass to synthetic intermediates. LÄS MER

  4. 3. Coordination of Phosphine-Thioether Ligands to Low-valent Metal Centers

    Författare :Roger Persson; Kemisk fysik; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; polynuclear metal complexes; fluxional behavior; cluster; thioether; phosphine; crystal structure; sulfur; triosmium;

    Sammanfattning : The reactivity of the phosphine-thioether ligands bis(2-diphenylphosphino) ethylthio)ethane (PSSP), bis(2-(diphenylphosphino) ethyl)sulfane (PSP), PPh2CH2CH2SMe (PS), PPh2(o-C6H4SMe (PortoS), and PPh(o-C6H4SMe)2 (PSS) towards low-valent carbonyl clusters has been studied. In all structurally characterized clusters, the ligand donor atoms are terminally coordinated. LÄS MER

  5. 4. Hydrodeoxygenation (HDO) catalysts Characterization, reaction and deactivation studies

    Författare :Houman Ojagh; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; Poisoning; Carbon deposition; Ring opening; Hydrodeoxygenation HDO ; Deactivation; Hydroconversion; Brønsted acid sites; Renewable diesel; Sulfided phase;

    Sammanfattning : Production of biomass derived fuels such as renewable diesel, are primarily intended to reduce the reliance of the conventional engines on petroleum fuels as well as the emission of CO2 from fossil hydrocarbons. Hydrodeoxygenation (HDO) is a powerful technique that has been regularly used in the fuel upgrading processes. LÄS MER