Sökning: "enamine"

Visar resultat 6 - 10 av 12 avhandlingar innehållade ordet enamine.

  1. 6. Development of catalytic enantioselective C-C bond-forming and cascade transformations by merging homogeneous or heterogeneous transition metal catalysis with asymmetric aminocatalysis

    Författare :Samson Afewerki; Armando Córdova; MICHELANGELO GRUTTADAURIA; Mittuniversitetet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; asymmetric catalysis; transition metals; aldehydes; heterogeneous catalysis; amino acid; organocatalysis; α-allylation; β-alkylation; dynamic transformations; polysubstituted; carbocycles; spirocyclic oxindoles; all-carbon quaternary stereocenters;

    Sammanfattning : Chiral molecules play a central role in our daily life and in nature, for instance the different enantiomers or diastereomers of a chiral molecule may show completely different biological activity. For this reason, it is a vital goal for synthetic chemists to design selective and efficient methodologies that allow the synthesis of the desired enantiomer. LÄS MER

  3. 7. Stereoselective syntheses of semichemicals : Applications in ecological chemistry

    Författare :Ellen M. Santangelo; Anna-Karin Borg-Karlsson; Olov Sterner; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; synthesis; semiochemical; pheromone; Lepidoptera; diene; Organisk kemi; Organic chemistry; Organisk kemi;

    Sammanfattning : This thesis describes the syntheses of semiochemicals and their applications in the development of control methods for pest insects. The compounds synthesized are divided into three groups: 1) Lepidoptera pheromones; 2) methyl substituted chiral pheromones and 3) aphid pheromones. LÄS MER

  4. 8. Studier av 2-cykloaminoindener speciellt med hänsyn till prototropa omlagringar

    Författare :Ulf Edlund; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : This thesis is a short review of six papers (Papers 1-6,page 5) concerning studies of enamines from 2-indanones. The unusually stable 2-(N-pyrrolidyl)indene has been studied (Paper 2 ). As a base catalyst this enamine rearranges 1-methylindene to 3-methylindene with a lower rate constant compared with triethylamine. LÄS MER

  5. 9. Optimering i organisk syntes : betingelser, system, syntesvägar

    Författare :Lars Hansson; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Optimization; Response surface method; PLS method; Silylation; Enolether; Unsaturated ketones; Diketones; Geosmin synthesis; Onepot procedure;

    Sammanfattning : This thesis deals with different optimization problems encountered in organic synthesis. The use of response surface, sequential simplex and PLS techniques, for simultanious optimization of yield and suppression of side reactions is investigated. This is illustrated by an example of enamine synthesis, were a side reaction was a serious problem. LÄS MER

  7. 10. Selective Transformations of Allylic Compounds and Enol Derivatives : Synthesis of Fluorinated and Nitrogenated Scaffolds

    Författare :Víctor García-Vázquez; Belén Martín‐Matute; Mario Waser; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Fluorinated compounds; Base catalysis; Ion-Pair; Isomerization; Pd catalysis; Method development; Hypervalent iodine III ; Organic Chemistry; organisk kemi;

    Sammanfattning : In this thesis, new synthetic methods to give access to molecules having fluorinated scaffolds and other polar functional groups have been developed. The methods give access to highly valuable organic compounds that may serve as building blocks in the synthesis of functionalized drug candidates. LÄS MER