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Hittade 2 avhandlingar som matchar ovanstående sökkriterier.

1. 1. Nickel and iridium pincer complexes with saturated frameworks - synthesis and reactivity

   Författare :Klara Jonasson; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; PCP complexes; aliphatic pincer ligands; coordination; cyclometallation; iridium; nickel; organometallic synthesis; CO2 activation; catalysis;

   Sammanfattning : As the tridentate chelate complexes referred to as pincer complexes have expanded their scope as homogeneous catalysts, there is an increased interest in electronic and steric fine-tuning of such complexes. One accessible variable in this aspect is the hybridisation of any coordinated carbon atoms. LÄS MER

3. 2. C–H activation through late transition metal cyclometallation. Addressing selectivity and reactivity problems

   Författare :Mikhail Kondrashov; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; C—H activation; cyclometallation; pincer ligands; anion exchange; bimetallic complexes; oxidative functionalisation;

   Sammanfattning : The ligand-directed C—H activation relies on a coordinating donor atom being in proximity to the C—H bond activated. Cyclometallation of 2-(1-naphthyl)-pyridine – a substrate containing both γ- and δ-positions in proximity to the directing nitrogen atom – was studied. LÄS MER