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1. 1. Probing Catalytic Reaction Mechanisms of Biomimetic Diiron Complexes through Time-resolved Absorption Spectroscopy

   Författare :Shihuai Wang; Leif Hammarström; Reiner Lomoth; Jillian Dempsey; Uppsala universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Artificial photosynthesis; Biomimetic catalysts; H2 formation; Catalytic intermediates;

   Sammanfattning : Directed design of improved molecular catalysts for hydrogen evolution reactions relies on rational benchmarking based on a detailed understanding about the mechanism of catalysis. Specifically, investigation of multi-electron redox catalysis, with structural characterization of catalytic intermediates, combined with the kinetics of their transformations, can reveal the rate-limiting step of the overall reaction, possible degradation pathways and the function of structural motives. LÄS MER