Sökning: "organometallic synthesis"
Visar resultat 16 - 20 av 31 avhandlingar innehållade orden organometallic synthesis.
16. Employment of Palladium Pincer Complex Catalysts and Lewis Acids for Synthesis and Transformation of Organometallic Compounds
Sammanfattning : This thesis is mainly focused on the development of new palladium catalyzed transformations using so-called “pincer” complexes. These complexes were applied as catalysts in two important areas of organometallic chemistry: substitution of propargylic substrates by dimetallic reagents; and allylation of aldehydes and imines by allylstannanes. LÄS MER
17. Green Chemical Synthesis of II-VI Semiconductor Quantum Dots
Sammanfattning : Nanotechnology is the science and technology of manipulating materials at atomic and molecular scale with properties different from bulk. Semiconductor QDs are important class of nanomaterials with unique physical and chemical properties owing to the quantum confinement effect. LÄS MER
18. Carbon Nanostructures – from Molecules to Functionalised Materials : Fullerene-Ferrocene Oligomers, Graphene Modification and Deposition
Sammanfattning : The work described in this thesis concerns development, synthesis and characterisation of new molecular compounds and materials based on the carbon allotropes fullerene (C60) and graphene.A stepwise strategy to a symmetric ferrocene-linked dumbbell of fulleropyrrolidines was developed. LÄS MER
19. Towards Rational Design of Asymmetric Catalyst for Organometallic and Organocatalytic Reactions
Sammanfattning : This thesis deals with synthetically modified chiral molecules and their application in asymmetric catalysis. The first part of the thesis describes the use of commercially available chiral diamine ligands in the iridium catalyzed transfer hydrogenation of aromatic ketones. LÄS MER
20. Unsymmetric PCN Pincer Palladium and Nickel Complexes : Synthesis, Characterization and Reactivity
Sammanfattning : New palladium and nickel complexes based on unsymmetric PCN pincer ligands have been synthesized and fully characterized using different techniques. The substituents on the nitrogen side arm of the ligand have great influence on the cyclometallation and the reactivity of the new complexes particularly in case of nickel. LÄS MER