Sökning: "organometallic synthesis"

Visar resultat 16 - 20 av 31 avhandlingar innehållade orden organometallic synthesis.

  1. 16. Employment of Palladium Pincer Complex Catalysts and Lewis Acids for Synthesis and Transformation of Organometallic Compounds

    Författare :Johan Kjellgren; Kálmán J. Szabó; Gerard van Koten; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Chemistry; Kemi;

    Sammanfattning : This thesis is mainly focused on the development of new palladium catalyzed transformations using so-called “pincer” complexes. These complexes were applied as catalysts in two important areas of organometallic chemistry: substitution of propargylic substrates by dimetallic reagents; and allylation of aldehydes and imines by allylstannanes. LÄS MER

  2. 17. Green Chemical Synthesis of II-VI Semiconductor Quantum Dots

    Författare :Robina Shahid; Mamoun Muhammed; Gunnar Westin; KTH; []
    Nyckelord :Semiconductor; Quantum Dots; Microwave; Ionic Liquids; Green Chemical Syntheis; Quantum Confinement; Optical Properties;

    Sammanfattning : Nanotechnology is the science and technology of manipulating materials at atomic and molecular scale with properties different from bulk. Semiconductor QDs are important class of nanomaterials with unique physical and chemical properties owing to the quantum confinement effect. LÄS MER

  3. 18. Carbon Nanostructures – from Molecules to Functionalised Materials : Fullerene-Ferrocene Oligomers, Graphene Modification and Deposition

    Författare :Michael Nordlund; Helena Grennberg; Mogens Brøndsted Nielsen; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Fullerenes; Graphene; Deposition; Functionalization; Organometallic complexes; Chemistry with specialization in Organic Chemistry; Kemi med inriktning mot organisk kemi;

    Sammanfattning : The work described in this thesis concerns development, synthesis and characterisation of new molecular compounds and materials based on the carbon allotropes fullerene (C60) and graphene.A stepwise strategy to a symmetric ferrocene-linked dumbbell of fulleropyrrolidines was developed. LÄS MER

  4. 19. Towards Rational Design of Asymmetric Catalyst for Organometallic and Organocatalytic Reactions

    Författare :Antti Hartikka; Per Arvidsson; Albrecht Berkessel; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organocatalysis; Transition Metal Complex; Asymmetric; Aldol Reaction; Cyclopropanation; Diels-Alder; Reduction; Conjugate Addition; Organic chemistry; Organisk kemi;

    Sammanfattning : This thesis deals with synthetically modified chiral molecules and their application in asymmetric catalysis. The first part of the thesis describes the use of commercially available chiral diamine ligands in the iridium catalyzed transfer hydrogenation of aromatic ketones. LÄS MER

  5. 20. Unsymmetric PCN Pincer Palladium and Nickel Complexes : Synthesis, Characterization and Reactivity

    Författare :Abdelrazek Mousa; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Unsymmetric PCN; Palladium; Nickel; Cyclometallation; Carboxylation; Cross-coupling;

    Sammanfattning : New palladium and nickel complexes based on unsymmetric PCN pincer ligands have been synthesized and fully characterized using different techniques. The substituents on the nitrogen side arm of the ligand have great influence on the cyclometallation and the reactivity of the new complexes particularly in case of nickel. LÄS MER