Sökning: "N-heterocyclic carbene NHC"

Visar resultat 1 - 5 av 12 avhandlingar innehållade orden N-heterocyclic carbene NHC.

  1. 1. Photoredox Catalysis Driven by Visible Light and Iron N-Heterocyclic Carbene Complexes

    Författare :Lisa de Groot; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; photoredox catalysis; iron N-heterocyclic carbene complexes; Fe-NHC; Visible light; ATRA; BHAS;

    Sammanfattning : Photoredox catalysis is a rapidly expanding field, in which organic transformations are catalysed using light. The most commonly used photoredox catalysts (PCs) are transition metal complexes which absorb in the visible region of the electromagnetic spectrum. LÄS MER

  3. 2. Aerobic Oxidative N-Heterocyclic Carbene Catalysis via Multistep Electron Transfer - Method Development and Applications

    Författare :Anton Axelsson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; N-heterocyclic carbene; asymmetric synthesis; esterification; glycerol; electron transfer mediator; green chemistry; telescoped reaction; Organocatalysis; aerobic oxidation; dihydropyranone;

    Sammanfattning : Oxidation reactions are ubiquitous in synthetic chemistry, but generally suffer from formation of large amounts of potentially toxic byproducts. Aerial oxygen represents an ideal oxidant since it is inexpensive, non-toxic and only forms water as a byproduct. LÄS MER

  4. 3. Structure-Property Relationships of Iron N-Heterocyclic Carbene Complexes : Synthesis, Characterization and Application

    Författare :Valtýr Freyr Hlynsson; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; photoredox catalysis; photovoltaics; photosensitizer; N-heterocyclic carbene NHC ; BHAS; synthesis; Organometallic chemistry; structure-property relationship; coordination chemistry; heteroleptic iron complexes; geometry; photophysics;

    Sammanfattning : Resulting from the general availability of first-row transition metals, compared to their second- and third-row counterparts, photosensitizers (PSs) based on metals like iron have gained interest as candidates to enable photochemistry from solar energy, a largely underutilized energy source. Iron complexes equivalent to other metal complexes, currently being used as PS, do lack some of the advantageous properties required to challenge the established PSs. LÄS MER

  5. 4. Development of Aerobic Oxidative N-Heterocyclic Carbene Catalysis via Multistep Electron Transfer and its Application

    Författare :Anton Axelsson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; dihydropyranone; Michael addition; kinetics.; aerobic oxidation; acylation; N-heterocyclic carbene; green chemistry; Organocatalysis; electron transfer mediator; asymmetric synthesis;

    Sammanfattning : Oxidation reactions are ubiquitous in synthetic chemistry, but generally suffer from formation of large amounts of potentially toxic byproducts. Aerial oxygen represents an ideal oxidant since it is inexpensive, non-toxic and only forms water as a byproduct. LÄS MER

  7. 5. N-Heterocyclic Carbene Catalysis in Organic Synthesis - A Green Chemistry Approach

    Författare :Linda Ta; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; aerobic oxidation; ionic liquid; sustainability; NHC catalysis; oxidative NHC catalysis; green chemistry; OTHO; Organocatalysis;

    Sammanfattning : The twelve principles of green chemistry were created as a response to the multiple environmental issues caused by the release of waste from the chemical industry. The principles acts as a guide in the development of sustainable chemical processes for the syntheses of important molecules needed to sustain our living standards. LÄS MER