Sökning: "Tellurium Compounds"

Visar resultat 1 - 5 av 8 avhandlingar innehållade orden Tellurium Compounds.

  1. 1. Exploring Catalytic Tellurium-Based Antioxidants : Synthesis and Evaluation

    Författare :Jia-fei Poon; Lars Engman; John Murphy; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; antioxidant; tellurium; selenium; radical-trapping; chain-breaking; ROS; glutathione peroxidase; tocopherol; aromatic amine; oxidative stress;

    Sammanfattning : This thesis is concerned with the synthesis and evaluation of various tellurium-based chain-breaking antioxidants. The purpose is to find novel regenerable compounds with improved radical-trapping capacity.In the first part of this work, we explore the possibilities to incorporate tellurium into tocopherols and aromatic amines. LÄS MER

  3. 2. Tellurium Behavior and Management in the Liquid Phases in the Containment During a Severe Nuclear Reactor Accident

    Författare :Anna-Elina Pasi; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; severe nuclear reactor accident; fission product; source term; tellurium;

    Sammanfattning : No industry is immune to accidents; however, the consequences and the probability are the parameters to consider when assessing the risks. When considering nuclear power, two of the highest-level accidents have occurred during the course of the commercial use of nuclear energy. LÄS MER

  4. 3. Regenerable Organochalcogen Antioxidants : An Explorative Study

    Författare :Jiajie Yan; Lars Engman; David J. Procter; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; autoxidation; antioxidant; selenium; tellurium; regenerable; multifunctional; radical-trapping; hydroperoxide-decomposing; co-antioxidant; Chemistry with specialization in Organic Chemistry; Kemi med inriktning mot organisk kemi;

    Sammanfattning : Antioxidants are widely used to protect organic materials from damages caused by autoxidation, an oxidation process that occurs under normal aerobic conditions. In this thesis, novel multifunctional organoselenium and organotellurium antioxidants were designed, synthesized, and evaluated in search for compounds with better radical-trapping capacity, regenerability, and hydroperoxide-decomposing ability. LÄS MER

  5. 4. Exploring Novel Catalytic Chalcogenide Antioxidants

    Författare :Henrik Johansson; Lars Engman; Helena Grennberg; Troels Skrydstrup; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; antioxidant; tellurium; selenium; catalytic; toxicity; ROS; neutrophil; glutathione peroxidase mimic; macrophage.; Organic chemistry; Organisk kemi; Kemi med inriktning mot organisk kemi; Chemistry with specialization in Organic Chemistry;

    Sammanfattning : This thesis is concerned with the synthesis and evaluation of regenerable chalcogen containing antioxidants. Variously substituted 2,3-dihydrobenzo[b]selenophene-5-ol antioxidants were evaluated in order to gain information about structure/reactivity-relationships. LÄS MER

  7. 5. A new synthetic strategy for low-dimensional compounds : Lone pair cations and alkaline earth spacers

    Författare :Rie Takagi Fredrickson; Mats Johnsson; Sven Lidin; Lars Kloo; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Alkaline earth; Lone pair elements; Low-dimensional compounds; Inorganic chemistry; Oorganisk kemi; oorganisk kemi; Inorganic Chemistry;

    Sammanfattning : Complex transition metals oxyhalides containing a lone pair element, such as tellurium (IV), form an attractive research field because there is a high probability of finding new low-dimensionally arranged compounds and, particularly, a low-dimensionally arranged transition metals substructures, leading to interesting physical properties. Tellurium (IV) can drive the formation of many unusual structures because of its stereochemically active lone pair electrons, E. LÄS MER