Sökning: "CATALYTIC MECHANISM"

Visar resultat 16 - 20 av 361 avhandlingar innehållade orden CATALYTIC MECHANISM.

  1. 16. Wiring Components of the Respiratory Chain : Modulation of the Respiratory Chain in Yeast and Bacteria

    Författare :Jacob Schäfer; Peter Brzezinski; Dennis Winge; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Cytochrome c oxidase; Electron transfer; Membrane protein; Ligand; Kinetics; Mechanism; Rcf1; Cytochrome c; Respiratory supercomplex; Cryo-electron microscopy; Biochemistry; biokemi;

    Sammanfattning : The enzyme complexes of the respiratory chain are organized in supramolecular assemblies, so-called respiratory supercomplexes. In the yeast Saccharomyces cerevisiae, these supercomplexes consist of two copies of complex III (bc1 complex) and one or two copies of complex IV (cytochrome c oxidase, CytcO). LÄS MER

  3. 17. Mechanistic investigation of platinum and palladium catalysed cross- coupling reactions. Implications for the Stille and Heck reactions

    Författare :Patrik Nilsson; Kemiska institutionen; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Metallorganisk kemi; Organometallic chemistry; Oorganisk kemi; Inorganic chemistry; parameter fitting; numerical solutions; platinum II ; palladium II ; NMR spectroscopy; transmetallation; Heck; Stille; kinetics; mechanism;

    Sammanfattning : The present thesis deals with various types of palladium(II) and platinum(II) complexes and their use in homogeneous catalysis. The focus has been devoted to mechanistic investigations concerning the Stille and Heck reactions and studies under both catalytic and stoichiometric conditions were conducted. LÄS MER

  4. 18. Ribosomal RNA Modification Enzymes : Structural and functional studies of two methyltransferases for 23S rRNA modification in Escherichia coli

    Författare :Avinash S. Punekar; Maria Selmer; Martino Bolognesi; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Escherichia coli; ribosome biogenesis; ribosome assembly; ribosomal RNA; peptidyltransferase center; domain V; post-transcriptional modification; methyltransferases; S-adenosyl-methionine; RlmM; Cm2498; RlmJ; m6A2030; X-ray crystallography; substrate recognition; substrate specificity; catalytic mechanism; evolution; Biology with specialization in Structural Biology; Biologi med inriktning mot strukturbiologi; Biokemi; Biochemistry;

    Sammanfattning : Escherichia coli ribosomal RNA (rRNA) is post-transcriptionally modified by site-specific enzymes. The role of most modifications is not known and little is known about how these enzymes recognize their target substrates. LÄS MER

  5. 19. Structure, Morphology, and Catalytic Properties of CuOx/CeO2 Model Catalysts

    Författare :Björn Skårman; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Synchrotron radiation; High-energy Diffraction; X-ray Absorption Fine Structure Spectroscopy.; Chemical technology and engineering; Kemiteknik och kemisk teknologi; Chemistry; Kemi; Material technology; Materiallära; materialteknik; X-ray photoelectron spectroscopy; Atomic force microscopy; Gatan Image Filter GIF ; Energy-filtered TEM; High-resolution electron microscopy; Inert gas condensation IGC ; rf Magnetron sputtering; Thermal activation; Batch reactor; Carbon monoxide oxidation; Surface sensitivity; Catalytic anisotropy; Growth; Nucleation; Topography; Roughness; Core-shell structures; Morphology; Nanostructured; Nanocomposite; Nanoparticles; Surface structure; Polycrystalline surfaces; Thin films; Copper oxide; Cerium dioxide CeO2 ; Ceria;

    Sammanfattning : Cerium dioxide, or ceria, is a chemically stable oxygen ion conducting material with a capacity to store and release oxygen, and is therefore extensively used in combustion catalysts. The Cu-Ce-O system has been identified as one of the most active catalysts for the combustion of carbon monoxide. LÄS MER

  7. 20. Dissecting function and catalytic mechanism of fungal lytic polysaccharide monooxygenases

    Författare :Bing Liu; Sveriges lantbruksuniversitet; Sveriges lantbruksuniversitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : Fungi use a complex and well-orchestrated enzyme machinery to degrade lignocellulose biomass, in which both hydrolytic and redox enzymes are involved. Lytic polysaccharide monoxygenases (LPMOs) are copper-dependent enzymes that cleave bonds in polysaccharides using oxidative mechanisms. LÄS MER