Sökning: "Stereocontrol"

Visar resultat 1 - 5 av 6 avhandlingar innehållade ordet Stereocontrol.

  1. 1. Photochemical Surface Functionalization : Synthesis, Nanochemistry and Glycobiological Studies

    Författare :Lingquan Deng; Olof Ramström; Javier Rojo; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Carbohydrates; Glycobiology; Carbohydrate-protein interactions; Perfluorophenylazide PFPA ; Photochemistry; Carbohydrate surface immobilization; Carbohydrate microarrays; Surface plasmon resonance SPR ; Quartz crystal microbalance QCM ; Atomic force microscopy AFM ; Glyconanomaterials; Concanavalin A Con A ; Cyanovirin-N CV-N ; 1-Glycosyl thiols; Mutarotation; 1-S-glycosylation; Stereocontrol;

    Sammanfattning : This thesis mainly deals with the development of photochemical approaches to immobilize carbohydrates on surfaces for glycobiological studies. These approaches have been incorporated into a number of state-of-the-art nanobio-platforms, including carbohydrate microarrays, surface plasmon resonance (SPR), quartz crystal microbalance (QCM), atomic force microscopy (AFM), and glyconanomaterials. LÄS MER

  3. 2. 1,4-allylic stereocontrol via palladium catalysis in the synthesis of some natural products

    Författare :Hans Schink; Uppsala universitet; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP;

    Sammanfattning : .... LÄS MER

  4. 3. Fast Chemistry by Microwave Heating : First Descriptions of Highly Enantioselective Microwave Protocols for Metal Catalysis; First Descriptions of in-situ Gas Generation for Fast Combinatorial Microwave Chemistry

    Författare :Nils-Fredrik K. Kaiser; C. O.; Uppsala universitet; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Pharmaceutical chemistry; Farmaceutisk kemi; Pharmaceutical chemistry; Farmaceutisk kemi; Organic Pharmaceutical Chemistry; organisk farmaceutisk kemi;

    Sammanfattning : Microwave heating was applied to different palladium-catalyzed allylic substitution reactions. The use of various nucleophiles demonstrated C-, N-, O- and S- nucleophilicity. High yields and stereopurities of the corresponding alkyls, amides, ethers and sulfones were afforded after only 30 – 120 s of heating. LÄS MER

  5. 4. The Use of N,P-Iridium and N,P-Palladium Complexes in Asymmetric Synthesis

    Författare :Wangchuk Rabten; Pher Andersson; Virginie Vidal; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Iridium; Asymmetric Hydrogenation; Palladium; Asymmetric Cycloisomerization and Hosomi-Sakurai Allylation; organisk kemi; Organic Chemistry;

    Sammanfattning : The work presented in this thesis concerns asymmetric catalysis using chiral N,P-ligands and iridium or palladium transition metals. The first part  (Chapters 2 and 3) highlights the N,P-iridium catalyzed asymmetric hydrogenation of 1,4-cyclohexadienes having functionalized or unfunctionalized substituents, including allylsilane side chains. LÄS MER

  7. 5. Metal Mediated Synthesis. Synthetic and Mechanistic Investigations of Conjugate Addition and Reductive Amination

    Författare :Anders Johansson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; halosilane; all-trans-geranylgeraniol; copper reagent; primary amines; S -geranylcitronellol; iminium salt; alfa; cuprate; beta-unsaturated; lithium iodide; borane dimethyl sulfide complex; reductive amination; conjugate addition;

    Sammanfattning : The thesis is divided into two separate parts, one treating conjugate addition and the other reductive aminations. The first part of the thesis is concerned with organocopper promoted conjugate addition to .alfa.,. LÄS MER