Sökning: "Aqueous solution"

Visar resultat 11 - 15 av 349 avhandlingar innehållade orden Aqueous solution.

  1. 11. Ion pairing and Langmuir-like adsorption at aqueous surfaces studied by core-level spectroscopy

    Författare :Victor Ekholm; Olle Björneholm; Jan-Erik Rubensson; Markus Ammann; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; XPS; Surface; Aqueous; Liquid jet; Langmuir;

    Sammanfattning : Surface-bulk equilibria for solutes in aqueous solutions are studied using X-ray Photoelectron Spectroscopy (XPS) with high surface and chemical sensitivity. In the first part, the results show a reduction of the biochemically relevant guanidinium ions’ surface propensity with the addition of disodium sulphate due to ion pairing with the strongly hydrated sulphate ion, which could have implications for protein folding. LÄS MER

  2. 12. Self Assembly of Hardwood Xylan -In Aqueous Solution and at Cellulosic Surfaces

    Författare :Peter Westbye; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; Solution properties.; Unbounded Lignin; Extraction; Harwood; Model Cellulose; Fractionation; Glucuronoxylan; Adsorption; Lignin Carbohydrate complexes; Agglomeration; Bonded Lignin;

    Sammanfattning : The climate change on our planet is an issue of great concern. The dignity of this issue was confirmed by the award of the international panel of climate change (IPCC) the Nobel peace prize. This problem arises from the way that we live our lives, how we produce energy, materials and chemicals from a fossil source. LÄS MER

  3. 13. Polyelectrolyte complexes of bottle brush copolymers : Solution and adsorption properties

    Författare :Shovsky Alexander; Per M. Claesson; Tommy Nylander; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Surface and colloid chemistry; Yt- och kolloidkemi;

    Sammanfattning : The aim of this thesis work was to systematically investigate the physico-chemical properties of polyelectrolyte complexes (PECs) formed by bottle brush and linear polyelectrolytes in solution and at solid / liquid interfaces. Electrostatic self-assembly of oppositely charged macromolecules in aqueous solution is a versatile strategy to construction of functional nanostructures with easily controlled properties. LÄS MER

  4. 14. Poly(Ethylene Oxide) Based Bottle-Brush Polymers and their Interaction with the Anionic Surfactant Sodium Dodecyl Sulphate : Solution and Interfacial Properties

    Författare :Joseph Iruthayaraj; Per M. Claesson; Regine v. Klitzing; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; PEO brush polymers; brush polymers; PEO; poly ethylene oxide ; polymer-surfactant; sodium dodecyl sulphate SDS ; Ellipsomtery; PEO-SDS interactions; Surface and colloid chemistry; Yt- och kolloidkemi;

    Sammanfattning : The aim of this thesis work is to study the physico-chemical properties of poly(ethylene oxide), PEO, based brush polymers both in solution and at solid/aqueous interfaces. The importance of studying the surface properties of brush polymers can be related to a broad spectrum of interfacial-related applications such as colloidal stability, lubrication, detergency, protein repellency to name a few. LÄS MER

  5. 15. Ions interacting with macromolecules : NMR studies in solution

    Författare :Yuan Fang; Istvan Furo; Monika Schönhoff; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; electrophoretic NMR; diffusion NMR; specific ion effects; Hofmeister; ion binding; Kemi; Chemistry;

    Sammanfattning : Specific ion effects, identified for more than hundred years, play an important role in a wide range of phenomena and applications. Several mechanisms such as direct ion interaction with molecules have been suggested to explain these effects, but quantitative experimental evidence remains scarce. LÄS MER