Sökning: "specific ion effects"
Visar resultat 1 - 5 av 104 avhandlingar innehållade orden specific ion effects.
1. Molecular Insight into Ion-Specific Interactions : Vibrational Sum Frequency Study of the Carboxylic Acid Moiety
Sammanfattning : Ion specific effects at charged interfaces find numerous applications in colloidal sciences and play a vital role in many biological processes. Despite having been studied for over a century, starting with the work of F. Hofmeister in the 1880s, a comprehensive molecular understanding remains elusive. LÄS MER
2. Single-photon multiple ionisation of atoms and molecules investigated by coincidence spectroscopy : Site-specific effects in acetaldehyde and carbon dioxide
Sammanfattning : In this thesis, multiple ionisation processes of free atoms and molecules upon single photon absorption are studied by means of a versatile multi-electron-ion coincidence spectroscopy method based on a magnetic bottle, primarily in combination with synchrotron radiation. The latter offered the possibility to access not only valence but also core levels, revealing processes, which promote the target systems into different charge states. LÄS MER
3. Theoretical Investigations of the Role of Ion-Ion Correlations and Ion-Specific Interactions in Electric Double Layers
Sammanfattning : Electric double layers are ubiquitous, arising in some form in almost every situation involving an interface with an aqueous electrolyte solution. In order to gain insight into the behavior of electrolytes and electric double layers, simple models of bulk and inhomogeneous electrolyte solutions are considered in this thesis. LÄS MER
4. Characterizing ions in solution by NMR methods
Sammanfattning : NMR experiments performed under the effect of electric fields, either continuous or pulsed, can provide quantitative parameters related to ion association and ion transport in solution. Electrophoretic NMR (eNMR) is based on a diffusion pulse-sequence with electric fields applied in the form of pulses. LÄS MER
5. Design of Cellulose-based Materials by Supramolecular Assemblies
Sammanfattning : Due to climate change and plastic pollution, there is an increasing demand for bio-based materials with similar properties to those of common plastics yet biodegradable. In this respect, cellulose is a strong candidate that is already being refined on a large industrial scale, but the properties differ significantly from those of common plastics in terms of shapeability and water-resilience. LÄS MER