Sökning: "High-Pressure X-Ray Photoelectron Spectroscopy"

Visar resultat 1 - 5 av 8 avhandlingar innehållade orden High-Pressure X-Ray Photoelectron Spectroscopy.

  1. 1. Surface Studies of Model Systems relevant for Pd and Ag Catalysts

    Författare :Natalia Martin; Synkrotronljusfysik; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; High Pressure X-ray Photoelectron Spectroscopy; X-ray Photoelectron Spectroscopy; alumina; Ag; NiAl; Pd; catalysis; model system; Surface X-ray Diffraction; Low Energy Electron Diffraction; Scanning Tunneling Microscopy; Fysicumarkivet A:2014:Martin;

    Sammanfattning : This PhD thesis reports on investigations of the atomic scale structure of model catalysts relevant for the catalytic oxidation of CO and methane over Pd, and NOx reduction over silver-alumina, important reactions in automotive catalysts. By using complementary experimental techniques such as X-ray Photoelectron Spectroscopy, High Pressure X-ray Photoelectron Spectroscopy, Surface X-ray Diffraction, Low Energy Electron Diffraction, Infrared Spectroscopy, and Scanning Tunneling Microscopy, combined with theoretical calculations, the work presented in this thesis aims at an atomistic characterization of the active sites for silver-alumina and Pd model catalysts which may help to the design of new and improved catalysts. LÄS MER

  2. 2. CO, CO2 and N2 hydrogenation reactions probed by operando x-ray photoelectron spectroscopy

    Författare :David Degerman; Anders Nilsson; Miquel Salmeron; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Operando Catalysis; Hydrogenation reactions; High-Pressure X-Ray Photoelectron Spectroscopy; Syngas; kemisk fysik; Chemical Physics;

    Sammanfattning : Catalytic reactions are essential for generating the chemical products required by the modern society. In particular, reactions related to clean energy storage and generation as well as fertilizer production are facilitated by catalysts. However, the processes are often insufficiently understood at a mechanistic level. LÄS MER

  3. 3. Atmospheric corrosion of the MgAl alloy AM50 in rheocast and high pressure diecast conditions - Influence of Microstructure, CO2 and NaCl

    Författare :Mehrdad Shahabi Navid; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; SEM; MgAl alloy; Atmospheric corrosion; High pressure diecast; XPS; XRD; Rheocast;

    Sammanfattning : The NaCl-induced atmospheric corrosion of the high pressure diecast (HPDC) MgAl alloy AM50 was investigated. Commercially pure (CP) Mg was used as the reference. Two levels of salt; i.e. LÄS MER

  4. 4. Model catalysts studied by x-rays, visible and infrared light

    Författare :Stefano Albertin; Synkrotronljusfysik; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; High Energy Surface X-ray Diffraction; X-ray Photoelectron Spectroscopy; oxidation; Pd 100 ; PdO; Ir 100 ; IrO2; in-situ; operando; Surface Optical Reflectance;

    Sammanfattning : This work is focused on the study of transition metal model catalysts for gas-phase heterogeneous catalysis, studied with light-based in-situ and operando techniques.Metallic model catalysts, such as Palladium (Pd) and Iridium (Ir) single crystals and in minor part deposited Rhodium (Rh), were studied using a combination of x-ray and non x-ray techniques. LÄS MER

  5. 5. Interfaces in Dye-Sensitized Solar Cells Studied with Photoelectron Spectroscopy at Elevated Pressures

    Författare :Susanna Kaufmann Eriksson; Anders Hagfeldt; Håkan Rensmo; Erik Johansson; Joachim Schnadt; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Dye-sensitized solar cells; interfaces; solvation; photoelectron spectroscopy; HPXPS; HP-HAXPES; liquid jet; Chemistry with specialization in Physical Chemistry; Kemi med inriktning mot fysikalisk kemi;

    Sammanfattning : With an increasing demand for renewable energy sources, research efforts on different solar cell technologies are increasing rapidly. The dye-sensitized solar cell (DSC) is one such technology, taking advantage of light absorption in dye molecules. LÄS MER