Sökning: "palladium-catalyzed reactions"

Visar resultat 11 - 15 av 49 avhandlingar innehållade orden palladium-catalyzed reactions.

  1. 11. Development of Palladium-Catalyzed Transformations Involving η1-Allypalladium Species

    Författare :Niclas Solin; Kálmán Szabó; Antonio M. Echavarren; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Palladium; Homogenous catalysis; Allylation; Electrophilic substitution; Density functional calculations; Organic chemistry; Organisk kemi;

    Sammanfattning : This thesis is focused on investigation of the structure, reactivity and isomerization reactions of η1-allylpalladium complexes, which are key intermediates in catalytic transformations. The first part of this thesis concerns the structure and reactivity of bis-allylpalladium complexes. LÄS MER

  3. 12. Palladium-catalyzed C-H functionalization of alkenes under oxidative conditions

    Författare :Johanna M Larsson; Kálmán Szabó; Eszter Borbas; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Organisk kemi;

    Sammanfattning : The unique properties of high oxidation state palladium have been used to develop new catalytic alkene C-H functionalization reactions. A Heck-type coupling based on the reactivity of palladium catalysts and diaryliodonium salts has been developed with broad synthetic scope and tolerance for functional groups that are ordinarily reactive in Pd0/PdII catalysis, for example, allylic acetates and aryl bromides. LÄS MER

  4. 13. Palladium-catalyzed Allylic C-H and C-OH Functionalization. Reactions of the Obtained Allylboronic Acids

    Författare :Rauful Alam; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : This thesis is focused on the studies of two major transformations. The first transformation deals with the development of palladium-catalyzed selective allylic trifluoroacetoxylation reactions based on C-H functionalization, whereas the second comprises the synthesis and isolation of allylboronic acids using diboronic acid B2(OH)4 as boron source. LÄS MER

  5. 14. Palladium(II)-Catalyzed Heck Reactions : Domino Reactions, Decarboxylations, Mechanistic Studies & Continuous Flow Applications

    Författare :Ashkan Fardost; Mats Larhed; Patrick Guiry; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; palladium II ; dft; reaction mechanisms; esi-ms; heck; decarboxylation; microwave; continuous flow;

    Sammanfattning : This thesis describes research efforts dedicated to the development of palladium(II)-catalyzed oxidative Heck and Heck/Suzuki domino reactions, and the applications of a new microwave heating technology, purpose-built for continuous flow in organic synthesis.Paper I describes the development of a ligand-modulated approach for attaching aryl groups to a chelating vinyl ether. LÄS MER

  7. 15. Catalytic Stereoselective Formation of C–O, C–C and C–B Bonds : A Voyage from Asymmetric Reactions Enabled by Lipases to Stereoselective Palladium-Catalyzed Oxidative Transformations of Enallenes

    Författare :Bin Yang; Jan Bäckvall; Matthias Beller; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Synthesis; Enzymatic kinetic resolution; Palladium; Allenes; Oxidative Transformations; Ruthenium; organisk kemi; Organic Chemistry;

    Sammanfattning : This thesis has been focused on enzymatic kinetic resolutions and stereoselective oxidative transformations of enallenes catalyzed by PdII.In the first part of the thesis, a detailed discussion on Candida antarctica lipase B (CALB)-catalyzed kinetic resolution (KR) of δ-functionalized alkan-2-acetates is shown. LÄS MER