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Visar resultat 1 - 5 av 33 avhandlingar som matchar ovanstående sökkriterier.

  1. 1. Zwitterionic Separation Materials for Liquid Chromatography and Capillary Electrophoresis : Synthesis, Characterization and Application for Inorganic Ion and Biomolecule Separations

    Författare :Wen Jiang; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Analytical chemistry; Zwitterionic; stationary phase; separation; liquid chromatography; capillary electrophoresis; sulfobetaine; modification; covalently bonded; graft polymerization; ζ-potential; Analytisk kemi; Analytical chemistry; Analytisk kemi;

    Sammanfattning : Liquid Chromatography (LC) and Capillary Electrophoresis (CE) are modern analytical techniques that play very important roles in many areas of modern science such as life science, biotechnology, biomedicine, environmental studies, and development of pharmaceutics. Even though these two techniques have existed and been subjected to studies for several decades, the developments of new separation materials for them are still very important till now in order to meet the different new demands for improvement from other disciplines in science. LÄS MER

  2. 2. Synthesis and Reactivity Studies of Zwitterionic Silenes and 2-Silenolates

    Författare :Tamaz Guliashvili; Henrik Ottosson; Kim M. Baines; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Silicon; Zwitterionic Silene; 2-Silenolate; Diels-Alder Reaction; Silacyclohexene; X-ray Crystallography; Organisk kemi; Organic chemistry; Organisk kemi;

    Sammanfattning : This thesis describes synthesis and reactivity studies of 2-amino-2-siloxysilenes and 2-silenolates, species that are strongly influenced by reversed Si=C bond polarization, i.e. an Siδ-=Cδ+ polarization as compared to the natural Siδ+=Cδ- polarization. LÄS MER

  3. 3. Lowcoordinated Silicon and Hypercoordinated Carbon : Structure and Stability of Silicon Analogs of Alkenes and Carbon Analogs of Silicates

    Författare :Anders M. Eklöf; Henrik Ottosson; Sten Lunell; Thomas Müller; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; silenes; zwitterionic silenes; silenolates; reverse polarization; natural resonance theory; hypervalent carbon; hypercoordinated carbon; thermolysis; lowcoordinated silicon; Organic chemistry; Organisk kemi;

    Sammanfattning : Quantum chemical studies on lowcoordinated group 14-16 compounds have been performed. This thesis focuses particularly on silenes influenced by reverse Siδ-=Cδ+ bond polarization. Hypercoordinated carbon compounds are also studied. LÄS MER

  4. 4. Antivirulent and antibiofilm salicylidene acylhydrazide complexes in solution and at interfaces

    Författare :Shoghik Hakobyan; Madeleine Ramstedt; Jean-Francois Boily; Mikael Elofsson; Marcus Textor; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Antivirulent; Antibiofilm; Hydrazones; Gallium; Pseudomonas aeruginosa; Type three secretion system; Equilibrium constant; Chemical equilibrium modelling; Spectrophotometric titration; UV-Vis;

    Sammanfattning : The growing bacterial resistance against antibiotics creates a limitation for using traditional antibiotics and requests development of new approaches for treatment of bacterial infections. Among the bacterial infections that are most difficult to treat, biofilm-associated infections are one of the most hazardous. LÄS MER

  5. 5. Surface characterization and manipulation of polyampholytic hydrogel coatings

    Författare :Feng-I Tai; Thomas Ederth; Bo Liedberg; Lei Ye; Linköpings universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Hydrogels; antifouling; charge-balanced material; polyampholytes; force measurements; polymer swelling; protein adsorption; patterning; plasmonics;

    Sammanfattning : This thesis is dedicated to building up fundamental knowledge about polyampholytic hydrogels, which are developed in our group for anti-fouling purposes. Charge-balanced polymers, where positive and negative charges balance each other, have emerged as interesting candidates for many applications in materials science. LÄS MER