Sökning: "zeolite acidity"
Visar resultat 1 - 5 av 11 avhandlingar innehållade orden zeolite acidity.
1. Kraft lignin valorization by hydrotreatment over Mo-based sulfided catalysts
Sammanfattning : The production of green fuels and chemicals from bio-based feedstock can suppress the dependency on fossil resources and help mitigate global climate challenges. Kraft lignin is a thermochemically modified natural lignin obtained from the pulping process as a byproduct. LÄS MER
2. Tuned acidity in zeotypes: A descriptor to unravel the direct conversion of methane to methanol
Sammanfattning : The catalyst's acidity is crucial in countless chemical reactions, and thus to tune this parameter means to take the lead on the desired catalytic reaction. Therefore, it is not surprising that zeolites have been used since decades as catalysts for their outstanding properties of solid acids. LÄS MER
3. Partial Oxidation of Methane over Functionalised Zeolites and Zeotypes
Sammanfattning : Partial oxidation of methane to methanol is an industrially important process that allows natural gas and biogas to be utilised for methanol-based production of chemicals or converted to liquid methanol fuel, which make transportation more facile. In this thesis, the activity for partial oxidation of methane to methanol over copper functionalised zeolites and silica supported copper is investigated using a three-step quasi-catalytic approach including catalyst activation, methane reaction and methanol extraction by water. LÄS MER
4. Partial methane oxidation: insights from first principles and micro-kinetics calculations
Sammanfattning : Partial methane oxidation is a much-desired reaction with some intriguing challenges. Not only is there a need to activate methane and oxygen, but there is also a need to control the selectivity and prevent over-oxidation to thermodynamically more stable products, like carbon dioxide and water. LÄS MER
5. A tandem Catalyst for hydrogenation of CO2 to light olefins — The role of the zeolite component
Sammanfattning : The catalytic conversion of waste CO2 into light olefins offers a sustainable pathway for green chemicals production in the future. Over a tandem catalyst with the bifunctional active sites for methanol synthesis (CTM) and methanol to olefins (MTO), CO2 can be efficiently converted via intermediate methanol into a mixture of light olefins (ethylene, propene, butene). LÄS MER