Sökning: "vibrational modes"
Visar resultat 1 - 5 av 62 avhandlingar innehållade orden vibrational modes.
1. Low-Energy Modes of Molecules and Atoms Chemisorbed on a Metal Surface. CO and O on Pt(111) Studied by Infrared Spectroscopy
Sammanfattning : This thesis is devoted to the investigation of low-energy metal-adsorbate vibrational modes of CO molecules and O atoms chemisorbed on a Pt(111) surface using infrared spectroscopy (IRS). The infrared selection rule states that only vibrational modes having a non-vanishing component of its dynamical dipole moment perpendicular to the surface can be directly excited using IRS, known as dipole-allowed modes. LÄS MER
2. Understanding the interactions between vibrational modes and excited state relaxation in garnet structured phosphors
Sammanfattning : This thesis concerns investigations of the local structural environments and vibrational dynamics of the three garnet type oxide phosphors Ce3+-doped Y3Al5O12 (YAG:Ce3+), Ca3Sc2Si3O12 (CSS:Ce3+), and Sr3Y2Ge3O12 (SYG:Ce3+), which show promising optical properties as luminescent materials used in solid state white lighting technologies. The study focuses on a comprehensive analysis of the nature of the long-range vibrations (phonons) in terms of local atomic and molecular motions of the garnet structure, as well as their dependence on the nature of the garnet chemical composition, Ce3+ concentration and temperature. LÄS MER
3. Structure-Specific Vibrational Modes of Isolated Biomolecules Studied with Mid- and Far-Infrared Laser Spectroscopy
Sammanfattning : Biomolecular structure elucidation is crucial for our detailed understanding of various biological processes, since there is an intimate relationship between the biomolecular function and structure. In this respect, isolated biomolecules, despite being outside of their natural environment, are perfect model systems for in-depth studies of various fundamental interactions that govern the formation of biomolecular structure. LÄS MER
4. Surface Vibrational and Electron Spectroscopy - Experiments and first-principle calculations
Sammanfattning : This work deals with interpretation of experimental surface spectroscopic data with the aid of first-principle calculations. Surface infrared reflection-absorption spectra as well as spectra from the electron spectroscopic methods photoemission and X-ray absorption are considered. LÄS MER
5. Vibrational Spectroscopy of Surface Adsorbates on Metal Surfaces. Experiments and Calculations
Sammanfattning : This work deals with a detailed analysis of the vibrational spectra of methoxy (CH3O-) and ethoxy (CH3CH2O-) on W(110) and Cu(100) single crystal surfaces. By using theoretical ab initio quantum mechanical modeling, it is demonstrated that an unprecedented quantitative understanding of the vibrational frequencies of a surface adsorbate can be obtained. LÄS MER