Sökning: "transition-metal compounds"

Visar resultat 1 - 5 av 112 avhandlingar innehållade orden transition-metal compounds.

1. 1. New Reactions with Allyl- and Allenylboron Reagents : Transition-Metal-Catalyzed and Transition-Metal-Free Carbon-Carbon Bond Formation Processes

   Författare :Dong Wang; Kálmán J. Szabó; Jianbo Wang; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; carbon-carbon bond formation; cross-coupling; organoboron compound; allylboron reagent; allylation; transition metal; metal carbene; allenylboron reagent; transition metal free; diazo compound; tosylhydrazone; quinone; organisk kemi; Organic Chemistry;

   Sammanfattning : Organoboron compounds have been widely used in carbon-carbon bond formation reactions in organic synthesis and catalysis. This thesis is focused on cross-coupling reactions of allyl-, allenylboronic acids and their ester derivatives via transition metal catalysis or transition-metal-free processes. LÄS MER

3. 2. Modeling Photofunctional Transition Metal Complexes

   Författare :Iria Bolano Losada; NanoLund: Centre for Nanoscience; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; density functional theory; earth-abundant; molecular dynamics; quantum chemistry; photosensitizer; photophysics; photochemistry; solar fuels; solar energy conversion; transition metal complexes;

   Sammanfattning : Transition metal complexes play a crucial role in solar energy conversion. These coordination compounds have promising applications in dye-sensitized solar cells and photocatalysis, with particular interest in solar fuel production. LÄS MER

4. 3. Tunable Magnetic Properties of Transition Metal Compounds

   Författare :Solveig Felton; Per Nordblad; Peter Svedlindh; John Chapman; Uppsala universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Magnetic properties; Transition metal compounds; Magnetic structure; Domain structure; SQUID-magnetometry; MFM; Magnetism; Magnetism;

   Sammanfattning : The magnetic properties of transition metal compounds have been studied using SQUID-magnetometry, magnetic force microscopy and Lorentz transmission electron microscopy. New magnetic materials have been found and their magnetic properties have been determined. How the magnetic properties of a material can be changed through e.g. LÄS MER

5. 4. Atomistic simulation and experimental studies of transition metal systems involving carbon and nitrogen

   Författare :Jiaying Xie; Seshadri Seetharaman; Oleg Ostrovski; KTH; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Transition metal carbides; Transition metal nitrides; Transition metal carbo-nitrides; Lattice inversion method; Interatomic potential; Atomistic simulation; Metallurgical process engineering; Metallurgisk processteknik;

   Sammanfattning : The present work was initiated to investigate the stability, structural and thermodynamic properties of transition metal carbides, nitrides and carbo-nitrides by atomistic simulations and experimentations. The interatomic pair potentials of Cr-Cr, Mn-Mn, Fe-Fe, C-C, Cr-C, Mn-C, Fe-C, Cr-Fe, Cr-N and Mn-N were inverted by the lattice inversion method and ab initio cohesive energies, and then employed to investigate the properties of Cr-, Mn- and Fe-carbides by atomistic simulations in this work. LÄS MER

7. 5. Transition metal-catalyzed allylic and vinylic functionalization : Method development and mechanistic investigations

   Författare :Johanna M. Larsson; Kálmán J. Szabó; Dennis G. Hall; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; palladium; copper; catalysis; Heck reaction; C-H functionalization; allylic substitution; silylation; borylation; trifluoromethylation; fluorination; mechanistic study; transition metal; alkene; allylic silane; allylic boronate; allylic fluoride; organisk kemi; Organic Chemistry;

   Sammanfattning : The use of small molecule building blocks in, for example, pharmaceutical research and new material development, creates a need for new and improved organic synthesis methods. The use of transition metals as mediators and catalysts opens up new reaction pathways that have made the synthesis of completely new compounds possible as well as greatly improved the synthetic routes to known compounds. LÄS MER