Sökning: "transition metal carbides"
Visar resultat 1 - 5 av 37 avhandlingar innehållade orden transition metal carbides.
1. Atomistic simulation and experimental studies of transition metal systems involving carbon and nitrogen
Sammanfattning : The present work was initiated to investigate the stability, structural and thermodynamic properties of transition metal carbides, nitrides and carbo-nitrides by atomistic simulations and experimentations. The interatomic pair potentials of Cr-Cr, Mn-Mn, Fe-Fe, C-C, Cr-C, Mn-C, Fe-C, Cr-Fe, Cr-N and Mn-N were inverted by the lattice inversion method and ab initio cohesive energies, and then employed to investigate the properties of Cr-, Mn- and Fe-carbides by atomistic simulations in this work. LÄS MER
2. Thermodynamic investigations of transition metal systems containing coabon and nitrogen
Sammanfattning : In view of the important applications of carbides and carbo-nitrides of transition metals in the heat-resistant and hard materials industries, the thermodynamic activities of Cr and Mn in the Cr-C, Fe-Cr-C, Mn-Ni-C and Mn-Ni-C-N systems have been studied in the present work by the use of the galvanic cell technique. CaF2single crystals were used as the solid electrolyte. LÄS MER
3. Reactivity of Transition-Metal Compounds from Electronic Structure
Sammanfattning : Transition-metal carbides (TMC's), nitrides, and sulfides belong to the class of materials known as transition-metal compounds (TMX's). Besides having intriguing properties, these materials are relevant for, e.g., growth and catalysis. LÄS MER
4. Low-temperature deposition of epitaxial transition metal carbide films and superlattices using C60 as carbon source
Sammanfattning : The transition metal carbides are chemical compounds with a unique set of propertiesused in many thin film applications. In this work, thin films of group 4-5 transitionmetal carbides and superlattices were deposited at low temperatures by simultaneousevaporation of C60 using either metal e-beam evaporation or d.c. magnetron sputtering. LÄS MER
5. A Theoretical Perspective on the Chemical Bonding and Structure of Transition Metal Carbides and Multilayers
Sammanfattning : The present thesis deals with a theoretical description of issues regarding chemical bonding, structure and stability of transition metal carbides and multilayered structures. First principles density functional theory has been used extensively to investigate the properties of alloyed solutions of transition metal carbides. LÄS MER