Sökning: "thermodynamic activity"

Visar resultat 1 - 5 av 75 avhandlingar innehållade orden thermodynamic activity.

  1. 1. Investigations intothe crystallization of butyl paraben

    Författare :Huaiyu Yang; Åke Rasmuson; Mårten Behm; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Butyl paraben; Solubility; Thermodynamic; Activity; Activity coefficient; Second order correlation; Liquid-liquid phase separation; Ternary phase diagram; Nucleation; Induction time; Free energy; Interfacial energy; Nuclei critical radius Cooling crystallization; Evaporation crystallization; Chemical engineering; Kemiteknik;

    Sammanfattning : In thisproject, solubility of butyl paraben in 7 puresolvents and 5 ethanol aqueous solvents has been determined at from 1 ℃to 50 ℃. Thermodynamic properties of butyl paraben have been measured by DifferentialScanning Calorimetey. LÄS MER

  3. 2. Thermodynamic Database for Zirconium Alloys

    Författare :Rosa Jerlerud Pérez; Bo Sundman; Arthur Motta; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Zirconium alloys; thermodynamic equilibrium; thermodynamic properties; binary system; ternary system; Gibbs energy; Thermo-Calc; Calphad; binary system; ternary system; Other materials science; Övrig teknisk materialvetenskap;

    Sammanfattning : For many decades zirconium alloys have been commonly used in the nuclear power industry as fuel cladding material. Besides their good corrosion resistance and acceptable mechanical properties the main reason for using these alloys is the low neutron absorption. LÄS MER

  4. 3. Thermodynamic Aspects on Inclusion Composition and Oxygen Activity during Ladle Treatment

    Författare :Johan Björklund; Pär Jönsson; Margareta Andersson; Leiv Kolbeinsen; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Ladle treatment; thermodynamics; inclusions; steel; slag; equilibrium; ladle treatment; vacuum; oxide activity; oxygen activity.; Metallurgical process and manufacturing engineering; Metallurgisk process- och produktionsteknik;

    Sammanfattning : Two industrial studies and one set of lab scale trials have been done. In addition, a theoretical study has been done. The main focus has been on non metallic inclusion composition during the ladle refining operation in industrial steel production. Sampling has been done together with careful inclusion determination. LÄS MER

  5. 4. Design, Synthesis and Thermodynamic Studies of Galectin Ligands

    Författare :Maria Luisa Verteramo; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; galectin; conformational entropy; solvation; thermodynamic; interaction; molecular recognition; thiodigalactoside; diastereomer; structure-based design;

    Sammanfattning : The signaling within and between cells in biology is governed by molecular recognition between natural or synthetic ligands and proteins. This thesis project aimed to investigate the thermodynamic properties of specific interaction between synthetic ligands and galectin proteins. LÄS MER

  7. 5. Thermodynamic investigations of transition metal systems containing coabon and nitrogen

    Författare :Lidong Teng; Seshadri Seetharaman; Tooru Matsumiya; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Materials science; thermodynamic activity; galvanic cell technique; transition metal carbides; transition metal nitrides; phase equilibrium; Materialvetenskap; Materials science; Teknisk materialvetenskap;

    Sammanfattning : In view of the important applications of carbides and carbo-nitrides of transition metals in the heat-resistant and hard materials industries, the thermodynamic activities of Cr and Mn in the Cr-C, Fe-Cr-C, Mn-Ni-C and Mn-Ni-C-N systems have been studied in the present work by the use of the galvanic cell technique. CaF2single crystals were used as the solid electrolyte. LÄS MER