Sökning: "thermo chemistry"

Visar resultat 1 - 5 av 39 avhandlingar innehållade orden thermo chemistry.

  1. 1. Biomolecule Trapping With Stimuli-Responsive Polymer Coated Nanostructures

    Författare :Justas Svirelis; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; biomolecule transportation; protein interaction; polymer brushes; quartz crystal microbalance with dissipation monitoring; fluorescence microscopy; Poly N-Isopropylacrylamide ; surface plasmon resonance; poly ethylene glycol ;

    Sammanfattning : Trapping biomolecules in nanosized gaps is of great interest in novel systems for single molecule analysis and membranes, which filter biomolecules. Current platforms are lacking in full functionality to facilitate biomolecule trapping and transport in their native environment and without covalent tethering to surfaces. LÄS MER

  3. 2. Exploring functionalization of colloidal silica for nanoparticle-stabilized emulsions

    Författare :Sanna Björkegren; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; thermo-responsive emulsions; functionalized colloidal silica; Pickering emulsions; NMR spectroscopy; surface activity; clouding;

    Sammanfattning : The main objective of this thesis was to evaluate how surface functionalized colloidal silica can be utilized in emulsions stabilized solely by particles, so called Pickering emulsions. To achieve this, water-dispersed silica nanoparticles were functionalized with hydrophilic and hydrophobic groups. LÄS MER

  4. 3. Poly(N-Isopropylacrylamide) Polymer Brush Functionalized Nanostructures as Thermo-Responsive Gating Systems for Protein Transportation

    Författare :Justas Svirelis; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; biomolecule transportation; Poly N-Isopropylacrylamide ; polymer brushes; fluorescence microscopy; thermo-responsive polymers; surface plasmon resonance;

    Sammanfattning : Controlling molecule translocation through nanosized gaps is of great interest in novel systems for single molecule analysis and biomolecular membranes. The molecular gating property of thermo-responsive end-grafted poly(N-isopropylacrylamide) (PNIPAM) polymer brushes on well-shaped gold-silica nanostructures is intended to be investigated for controlled protein transportation via extinction spectroscopy and fluorescence microscopy methods below and above PNIPAM lower critical solution temperature (LCST; 32 °C in water). LÄS MER

  5. 4. Biomimetic Transition Metal Catalysts : Insights from Theoretical Modeling

    Författare :Adam Johannes Johansson; Per E. M. Siegbahn; Margareta R. A. Blomberg; Per-Ola Norrby; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Catalysis; biomimetic; copper; non-heme iron; heme iron; O2 cleavage; H-atom transfer; radical chemistry; redox chemistry; thermo chemistry; entropy calculations; quantum chemistry; spin states; density functional theory DFT ; self-interaction error SIE .; Chemical physics; Kemisk fysik; kemisk fysik; Chemical Physics;

    Sammanfattning : The scientific interest in the chemistry of synthetic transition metal complexes is motivated by at least two arguments:1.These can be regarded as models of biological transition metal complexes, e.g. metalloenzymes, whose functions can be difficult to reveal in detail due to their complexity. LÄS MER

  7. 5. Towards a retro-structural design of degradable aliphatic polyester-based materials

    Författare :Veluska Arias; Ann-Christine Albertsson; Minna Kellomäki; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Hydrolysis; polyesters; polylactide; hydrophobicity; crystallinity; miscibility; nanoparticles; stereocomplex; homocomposites; Kemi; Chemistry;

    Sammanfattning : The increasing amount of accumulated plastic waste has led to a continuous search for degradable materials for use in a variety of applications. This eco-friendly approach contemplates the use of degradable alternatives to the inert polymers (the main components in plastics) used today and further engineering of their degradation pathways. LÄS MER