Sökning: "surfactant association"

Visar resultat 1 - 5 av 39 avhandlingar innehållade orden surfactant association.

1. 1. Polyelectrolytes : Bottle-Brush Architectures and Association with Surfactants

   Författare :Ali Naderi; Per M. Claesson; Orlando Rojas; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polyelectrolyte; Surfactant; Bottle-Brush Polyelectrolyte; Comb Polyelectrolyte; Non-Equilibrium State; Polymer Architecture; Adsorption; Desorption; Association; Excluded Volume; Light Scattering; SFA; AFM; QCM-D; Turbidimeter; Mica; Silica; Surface Forces; Surface and colloid chemistry; Yt- och kolloidkemi;

   Sammanfattning : This thesis has the dual purpose of raising awareness of the importance of the mixing protocol on the end products of polyelectrolyte-oppositely charged surfactant systems, and to contribute to a better understanding of the properties of bottle-brush polyelectrolytes when adsorbed onto interfaces. In the first part of this thesis work, the effects of the mixing protocol and the mixing procedure on formed polyelectrolyte-oppositely charged surfactant aggregates were investigated. LÄS MER

3. 2. Association Phenomena Involving Hydrophobically Modified Polymers. Electrostatic and Hydrophobic Contributions

   Författare :Marina Tsianou; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; scaling; light scattering; rheology; aqueous solution behavior; phase behavior; cyclodextrin; surfactant; polyacrylate; cellulose ether; polyelectrolyte; hydrophobically modified polymer; Polymer; water soluble polymer; viscosity; association; segregation; Physical chemistry; Fysikalisk kemi;

   Sammanfattning : The electrostatic and hydrophobic interactions in aqueous solutions of hydrophobically-modified water-soluble non-ionic or ionic polymers, their mixtures with a second polymer, nonionic or of opposite charge, and their mixtures with surfactants of opposite charge have been investigated. The relative strength of the electrostatic and hydrophobic contributions has been modulated by a variation of the polymer charge density and the solution pH, and by a variation in the degree and strength of the hydrophobic modifications, respectively. LÄS MER

4. 3. Association and Interactions in Protein-Surfactant Systems

   Författare :Anna Stenstam; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; catanionic surfactant; SANS; NMR; gel; sodium alkylsulfate; Protein-surfactant interactions; lysozyme; LH2; Physical chemistry; Fysikalisk kemi;

   Sammanfattning : Aggregation in protein-surfactant systems have been studied with the ambition of reaching a deeper understanding of the balance of the interaction forces involved. A pure system with maximized electrostatic interactions has been used. LÄS MER

5. 4. Molecular Association Studied by NMR Spectroscopy

   Författare :Lars Nordstierna; István Furó; Peter Griffiths; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NMR; spin relaxation; self-diffusion; intermolecular cross-relaxation; chemical shift; fluorinated surfactants; hydrogenated surfactant; micelle; non-ideal mixing; adsorption; hydration; surfactant-protein association; Physical chemistry; Fysikalisk kemi;

   Sammanfattning : This Thesis presents studies of molecular association in aqueous solution and at the liquid/solid interface. The investigated molecular systems range from self-aggregating surfactants to hydration water in contact with micelles or individual molecules. In most studies, combinations of various NMR methods were applied. LÄS MER

7. 5. NMR Diffusion Studies of Association in Surfactant Systems Inclusion Complexes, Micellar Solutions and Microemulsions

   Författare :Markus Nilsson; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; host-guest complexation; gemini surfactant; cyclodextrin; bolaform surfactant; self-diffusion NMR; pluronic; bicontinuous microemulsion; polydispersity; boosting effect;

   Sammanfattning : The aim of this thesis has been to investigate self-diffusion behavior of host-guest complex, microemulsion and polymer solution. Pulsed Field Gradient NMR (PFG-NMR) was shown to provide detailed molecular information in all system studied. LÄS MER