Sökning: "supercritical flow"
Visar resultat 1 - 5 av 19 avhandlingar innehållade orden supercritical flow.
1. Turbulence modeling of compressible flows with large density variation
Sammanfattning : In this study we highlight the influence of mean dilatation and mean density gradient on the Reynolds stress modeling of compressible, heat-releasing and supercritical turbulent flows.Firstly, the modeling of the rapid pressure-strain correlation has been extended to self-consistently account for the influence of mean dilatation. LÄS MER
2. Palladium(0)-Catalyzed Synthesis of Spirocycles and Supercritical Chemistry using a Resistively Heated Flow Reactor
Sammanfattning : This doctoral thesis focusses on an effective and selective approach to the synthesis of spirocycles using palladium(0)-catalyzed Mizoroki-Heck reactions. In addition, selective and efficient chemistry was highlighted by the design and evaluation of a novel resistively heated system for continuous flow (CF) synthesis for high-temperature and high-pressure applications. LÄS MER
3. Lipase-Catalysed Lipid Modifications in Supercritical Carbon Dioxide
Sammanfattning : The production of ethyl esters (EE) from ethanol and cod-liver oil by an immobilised lipase in supercritical carbon dioxide (SCCO2) is described. This reaction results in a complex mixture of lipid components consisting of triglycerides, diglycerides, monoglycerides and ethyl esters. LÄS MER
4. Fundamental research on supercritical fluid extraction kinetics : From on-line measurements to inverse modeling
Sammanfattning : Supercritical fluid extraction is an extraction technique suitable for lipophilic compounds from solid samples. Most commonly supercritical carbon dioxide is the main component in the extraction phase, rendering the technique relatively environmentally benign. LÄS MER
5. Microfluidics at High Pressures : Understanding, Sensing, and Control
Sammanfattning : This thesis explores understanding, sensing, and control in high-pressure microfluidics. The high-pressure regime allows fluids to be forced through narrow channels at substantial speed and creates conditions for fluids of high density and low viscosity—features desired in flow-based chemical analyses. LÄS MER