Sökning: "substituted 1"

Visar resultat 11 - 15 av 239 avhandlingar innehållade orden substituted 1.

  1. 11. Silaborations of Unsaturated Compounds

    Författare :Martin Gerdin; Christina Moberg; Kálmán Szabó; KTH; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; allylboration; bismetallation; boron; carbocyclization; catalysis; 1; 3-diene; enantioselective; 1; 6-enyne; interelement; N-heterocyclic carbene; nickel; palladium; phosphine; phosphoramidite; platinum; reaction mechanism; silaboration; silicon; silylborane; stereoselective; Chemistry; Kemi;

    Sammanfattning : This thesis deals with the development of transition metal-catalyzed silaborations of 1,3-dienes and 1,6-enynes. The first part of the thesis describes the development of the enantioselective 1,4-silaboration of 1,3-cyclohexadiene. A number of chiral metal-ligand complexes were evaluated. LÄS MER

  3. 12. Palladium(II)-catalyzed 1,4-oxidations of 1,3-dienes : Development of an asymmetric version and synthetic applications

    Författare :Andreas Palmgren; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Chemistry; Kemi; Chemistry; Kemi; organisk kemi; Organic Chemistry;

    Sammanfattning : In this thesis the development of an asymmetric version and synthetic applications of the Pd(II)-catalyzed 1,4-oxidation of conjugated dienes are described. The thesis is divided into four parts:(i) The first part concerns the design and synthesis of chiral p-benzoquinones as ligands in the Pd(II)-catalyzed 1,4-diacetoxylation. LÄS MER

  4. 13. Making Radical Cations Live Longer

    Författare :Ola Persson; Kemisk fysik; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; spin trapping.; 3-hexafluoropropan-2-ol; 3; 1; thallium III -based oxidants; Radical cations; electron paramagnetic resonance; Physics; Fysik; Chemistry; Kemi;

    Sammanfattning : The acid-catalyzed rearrangement of 1,4,5,8-tetramethylnaphthalene was used to determine the acidity of media used for EPR spectral studies of radical cations. The radical cations of methyl-substituted naphthalenes were shown to undergo dimerization reactions. LÄS MER

  5. 14. Natural Product Synthesis and Development of Novel Reaction Methodology

    Författare :Jakob Danielsson; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; perophoramidine; communesin; quaternary stereocenter; Diels-Alder; 1; 2-asymmetric induction; polar Felkin-Anh; Cornforth-Evans; Mukaiyama aldol; 3-dipolar cycloaddition; azomethine ylide; 2-amino alcohol; anti-α-amino-β-hydroxy ester;

    Sammanfattning : This thesis deals with the development of new reaction methodology for stereoselective synthesis, as well as total synthesis of natural products and investigations of the stereochemical outcome in the Mukaiyama aldol reaction. Chapter 2 describes efforts made towards the total synthesis of the oxindole natural products perophoramidine and the communesin. LÄS MER

  7. 15. Synthesis of amino- and hydroxyl-substituted bridged bicyclic compounds and their application in asymmetric catalysis

    Författare :Cecilia Olsson; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; organocatalysis; asymmetric catalysis; bicyclo[2.2.1]heptane; bicyclo[2.2.2]octane; dibenzobicyclo[3.3.1]nonane; bioreduction; enzymatic kinetic resolution;

    Sammanfattning : In this work, hydroxyl- and amino-substituted bridged bicyclic compounds based on bicyclo[2.2.1]heptane, bicyclo[2.2. LÄS MER