Sökning: "spirocyclic initiator"

Hittade 3 avhandlingar innehållade orden spirocyclic initiator.

  1. 1. Design of polyester and porous scaffolds

    Författare :Karin Odelius; Ann-Christine Albertsson; Monica Ek; Torbjörn Mathisen; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; ring-opening polymerization; porous scaffold; L-lactide; 5-dioxepane-2-one; ε-caprolactone; spirocyclic initiator; star-shaped polyester; Polymer chemistry; Polymerkemi;

    Sammanfattning : The use of synthetic materials for tissue and organ reconstruction, i. e. tissue engineering, has become a promising alternative to current surgical therapies and may overcome the shortcomings of the methods in use today. LÄS MER

  3. 2. Macromolecular design and architecture of aliphatic polyesters

    Författare :Karin Odelius; Ann-Christine Albertsson; Helmut Keul; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Ring-opening polymerization; L-lactide; 1; 5-dioxepane-2-one; ε-caprolactone; Polymerization kinetics; Star-shaped architecture; Spirocyclic tin initiator; Polymer chemistry; Polymerkemi;

    Sammanfattning : Public health care has reached a level where tissue or organ reconstruction by means of biodegradable short-term implants via e.g. tissue engineering will be practicable in the near future. LÄS MER

  4. 3. Novel Possibilities for Advanced Molecular Structure Design for Polymers and Networks

    Författare :Anna Finne; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; ring-opening polymerization; coordination-insertion; germanium; cyclic tin alkoxides; spirocyclic initiators; poly L-lactide ; poly 1; 5-dioxepan-2-one ; triblock; star-shaped; network; functionalization; morphology; AFM; Polymer chemistry; Polymerkemi;

    Sammanfattning : Synthetic and degradable polymers are an attractive choicein many areas, since it is possible to control the way in whichthey are manufactured; more specifically, pathways tomanipulate the architecture, the mechanical properties and thedegradation times have been identified. In this work,L-lactide, 1,5-dioxepan-2-one and ε-caprolactone were usedas monomers to synthesize polymers with different architecturesby ring-opening polymerization. LÄS MER