Sökning: "secondary alcohols"

Visar resultat 16 - 20 av 56 avhandlingar innehållade orden secondary alcohols.

  1. 16. Computational Studies of Transition Metal-Catalyzed Asymmetric Transfer Hydrogenation Reactions

    Författare :Mikael Nordin; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; organisk kemi; Organic Chemistry;

    Sammanfattning : This thesis is based on two studies dealing with the computational investigation of asymmetric transfer hydrogenation reactions, in which hydrogen is transferred from a donor molecule (e.g. alcohol) to a substrate (ketone), via mediation of a metal-ligand catalyst complex. LÄS MER

  3. 17. Biotransformations of Turpentine Constituents : Oxygenation and Esterification

    Författare :Marica Lindmark-Henriksson; KTH; []
    Nyckelord :Picea abies; Pinaceae; Essential oils composition; Terpene alcohol; Hemiacetal; Hemiacetal ester; TMP-turpentine; Monoterpene; alpha-pinene; beta-pinene; Limonene; Verbenol; Pinocarveol; Borneol; Myrtenol; Suspension cell culture; Biotransformation; ;

    Sammanfattning : This thesis describes methods to obtain value–addedcompounds from TMP-turpentine obtained from the spruce, Piceaabies. The methodology focuses on biotransformations using twoapproaches: an oxygenation approach (i.e. oxygenation ofterpene hydrocarbons by cell cultures) and an esterificationapproach (i. LÄS MER

  4. 18. Transition Metal-Catalyzed Redox Reactions : A Journey from Homogeneous Ruthenium to Heterogeneous Palladium Catalysis

    Författare :Oscar Verho; Jan-Erling Bäckvall; Manfred Reetz; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; organisk kemi; Organic Chemistry;

    Sammanfattning : The first part of the thesis covers the development and utilization of electronically modified (pentaarylcyclopentadienyl)Ru-complexes in the racemization of secondary alcohols. This study revealed that the electronic properties of the substrate were the main factors dictating whether β-hydride elimination or hydride re-addition becomes the rate-determining step of the racemization process. LÄS MER

  5. 19. Enantioselective Synthesis of Sec-Alcohol Derivatives and Diols via Combined Ruthenium and Enzyme Catalysis

    Författare :Linnéa Borén; Jan-Erling Bäckvall; Romas Kazlauskas; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; catalysis; kinetic resolution; ruthenium catalyst; Dynamic kinetic resolution; Dynamic Kinetic Asymmetric Transformation; Organic chemistry; Organisk kemi; Organic Chemistry; organisk kemi;

    Sammanfattning : The first part of this thesis describes the synthesis of enantiopure secondary alcohol derivatives. These syntheses are carried out via the combination of an enzyme as a resolution catalyst and a ruthenium catalyst as a racemization catalyst, in what is called dynamic kinetic resolution (DKR). LÄS MER

  7. 20. Transition metal-catalyzed hydrogen transfer processes

    Författare :Oscar Verho; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : The first part describes the synthesis of new analogues of Bäckvall’s catalyst with varying electronic properties and their application in the racemization of sec-alcohols. The racemization involves two key steps: (i) β-hydride elimination (dehydrogenation of the alcohol) and (ii) hydride re-addition to the intermediate ketone. LÄS MER