Sökning: "ruthenium"

Visar resultat 11 - 15 av 190 avhandlingar innehållade ordet ruthenium.

  1. 11. Ruthenium-Manganese Complexes as Model Systems for Artificial Photosynthesis

    Författare :Anh Tran; KTH; []
    Nyckelord :Oligopyridine; bipyridine; terpyridine; ligand synthesis; ruthenium; manganese; dipicolylamine; phenolate ligands; phosphonate; artificial photosynthesis; photosystem II;

    Sammanfattning : .... LÄS MER

  3. 12. Ruthenium-Catalyzed Hydrogen Transfer Reactions : Mechanistic Studies and Chemoenzymatic Dynamic Kinetic Resolutions

    Författare :Madeleine Warner; Jan-Erling Bäckvall; Andreas Pfaltz; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Hydrogen transfer; ruthenium catalysis; kinetic resolution; dynamic kinetic resolution; racemization; asymmetric synthesis; organisk kemi; Organic Chemistry;

    Sammanfattning : The main focus of this thesis lies on transition metal-catalyzed hydrogen transfer reactions. In the first part of the thesis, the mechanism for racemization of sec-alcohols with a ruthenium complex, Ru(CO)2Cl(η5-C5Ph5) was studied. LÄS MER

  4. 13. Ruthenium-catalyzed redox reactions and lipase-catalyzed asymmetric transformations of alcohols

    Författare :Michaela Edin; Jan-E. Bäckvall; Manfred T. Reetz; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; ruthenium; lipase; catalysis; alcohols; diols; Chemistry; Kemi;

    Sammanfattning : The major part of this thesis describes the synthesis of enantiopure alcohols and diols by combining ruthenium-catalyzed redox reactions that lead to racemization or epimerization and lipase-catalyzed asymmetric trans-formations in one-pot.A mechanistic study of the unexpected facile formation of meso-diacetate products found in enzyme-catalyzed acetylations of alkanediols with Candida antarctica lipase B (CALB) was first performed. LÄS MER

  5. 14. Synthesis and asymmetric transformations of diols by enzyme- and ruthenium catalysis

    Författare :Karin Leijondahl; Jan-Erling Bäckvall; Kurt Faber; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; dynamic kinetic asymmetric transformation; diols; enzymatic transformations; catalysis; ruthenium; transfer hydrogenation; Organic chemistry; Organisk kemi; Organic Chemistry; organisk kemi;

    Sammanfattning : The major part of this thesis describes the synthesis of aliphatic secondary diols and the development of lipase- and ruthenium-catalyzed asymmetric transformations of these diols. Several acyclic 1,4-diols and 1,5-diols were synthesized, and by combining a lipase-catalyzed asymmetric transformation with a ruthenium-catalyzed epimerization, enantiomerically- and diastereomerically enriched diacetates were obtained. LÄS MER

  7. 15. Diastereomeric Effects in DNA Binding – Biological and Biophysical Studies on Ruthenium Complexes

    Författare :Anna Mårtensson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; neighbor interaction; spectroscopy; diastereomeric; kinetics; antimicrobial activity; ruthenium; calorimetry; intercalation; DNA; enantiomer;

    Sammanfattning : Organic molecules, such as glucose and amino acids, are most often chiral. This means that their mirror-images are different, in the same way a left and a right hand are different from each other. For example, the DNA double helix in its standard form twists like a right-handed screw. LÄS MER