Sökning: "pyrrolidine"

Visar resultat 6 - 10 av 26 avhandlingar innehållade ordet pyrrolidine.

  1. 6. 1. Asymmetric aldol and alkylation reactions using pyrrolidine-based chiral auxiliaries 2. Syntheses of pine sawfly pheromone precursors and structurally related compounds

    Författare :Fredrik Andersson; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Chiral auxiliary; Stereoselectivity; Lewis acid; Aldol; Alkylation; Sex pheromone; Pine sawfly; Lipase; Synthesis; Chemistry; Kemi;

    Sammanfattning : .... LÄS MER

  3. 7. Carbon Nanostructures – from Molecules to Functionalised Materials : Fullerene-Ferrocene Oligomers, Graphene Modification and Deposition

    Författare :Michael Nordlund; Helena Grennberg; Mogens Brøndsted Nielsen; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Fullerenes; Graphene; Deposition; Functionalization; Organometallic complexes; Chemistry with specialization in Organic Chemistry; Kemi med inriktning mot organisk kemi;

    Sammanfattning : The work described in this thesis concerns development, synthesis and characterisation of new molecular compounds and materials based on the carbon allotropes fullerene (C60) and graphene.A stepwise strategy to a symmetric ferrocene-linked dumbbell of fulleropyrrolidines was developed. LÄS MER

  4. 8. Stereoselective Nucleophilic Additions to α-Amino Aldehydes: Application to Natural Product Synthesis

    Författare :Per Restorp; Peter Somfai; Timothy J. Donohoe; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Stereoselective synthesis; Substrate-control; α-Amino aldehydes; Mukaiyama aldol; Allylsilanes; [3 2]-Annulation; -Alexine; DGDP; Vinyl epoxides; Regioselectivity; Alkyne nucleophiles; Organic chemistry; Organisk kemi;

    Sammanfattning : This thesis deals with the development and application of new synthetic methodology for stereo- or regioselective construction of carbon-carbon bonds in organic synthesis. The first part of this thesis describes the development of a divergent protocol for stereoselective synthesis of chiral aminodiols by employing Mukaiyama aldol additions to syn- and anti-α-amino-β-silyloxy aldehydes. LÄS MER

  5. 9. Phosphine ligands with triamine functionality - preparation and application in catalysis

    Författare :Magnus Karlsson; Enheten för fysikalisk och teoretisk kemi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Inorganic chemistry; water soluble; palladium; amphiphilic; rhodium; Oorganisk kemi;

    Sammanfattning : Incorporation of the triamine, bis(2-diethylaminoethyl) amine as a side chain substituent on triphenylphosphine, (2S,4S)-4-diphenylphosphino-2-diphenylphosphino-methylpyrrolidine (PPM) or (R,R)-3,4-bis(diphenylphosphin)pyrrolidine (Pyrphos) gives the three new amphiphilic ligands N3P, N3PPM and N3-Pyrphos respectively. Because of the triamine functionality the distribution of the ligands and their complexes between water and an organic solvent is controlled by the pH of the aqueous phase. LÄS MER

  7. 10. Chiral Pyridine-Containing Ligands for Asymmetric Catalysis. Synthesis and Applications

    Författare :Fredrik Rahm; KTH; []
    Nyckelord :asymmetric catalysis; chiral ligand; chiral pool; oxazoline; crown ether; ditopic receptor; bipyridine; pyridyl alcohol; modular approach; P; N-ligand; diethylzinc; allylic alkylation;

    Sammanfattning : This thesis deals with the design and syntheses of chiral,enantiopure pyridinecontaining ligands and their applicationsin asymmetric catalyis.Chiral pyridyl pyrrolidine ligands and pyridyl oxazolineligands were synthesized and employed in thepalladium-catalysed allylic alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate. LÄS MER