Sökning: "pyrazine"

Visar resultat 1 - 5 av 9 avhandlingar innehållade ordet pyrazine.

  1. 1. Multiconfigurational perturbation theory

    Författare :Kerstin Andersson; Karlstads universitet; []
    Nyckelord :Electron correlation; CASSCF; multiconfigurational second-order perturbation theory; CASPT2; ozone; C; N; O; F; Si; P; S; Cl; Ni; benzene; pyridine; pyrazine; pyrimidine; pyridazine; s-triazine; electric properties; excited states; spectroscopic data;

    Sammanfattning : The aim of the thesis is to analyze a method which describes the electron correlation in atoms and molecules. The method is based on Rayleigh-Schrödinger perturbation theory with a partitioning of the Hamiltonian into a fairly simple zeroth-order operator and a perturbation operator. LÄS MER

  3. 2. Reaction Between Grignard reagents and Heterocyclic N-oxides : Synthesis of Substituted Pyridines, Piperidines and Piperazines

    Författare :Hans Andersson; Fredrik Almqvist; Hans Adolfsson; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Grignard reagents; pyridine N-oxide; pyrazine N-oxide; dienal-oxime; pyridine; ortho- metalation; piperidine; piperazine; asymmetric; Organic synthesis; Organisk syntes; organisk kemi; Organic Chemistry;

    Sammanfattning : This thesis describes the development of new synthetic methodologies for preparation of bioactive interesting compounds, e.g. substituted pyridines, piperidines or piparazines. Thesecompounds are synthesized from commercially available, cheap and easily prepared reagents, videlicet the reaction between Grignard reagents and heterocyclic N-oxides. LÄS MER

  4. 3. Synthesis and Characterisation of Conjugated Polymers with High Electron Affinity

    Författare :Maria Jonforsen; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; light-emitting diode; solar cell; quinoxaline; conjugated polymer; photodiode; 4-b]pyrazine; pyrido[3; synthesis; photo-oxidation; electron affinity; pyridine;

    Sammanfattning : This thesis describes synthesis and characterisation of conjugated polymers with high electron affinities. Polymers of this type are desired, for example, for use in light-emitting devices or as electron accepting material in photodiodes/solar cells. LÄS MER

  5. 4. Synchrotron radiation studies of gas phase molecules : from hydrogen to DNA sugars

    Författare :Gemma Vall-llosera; Elisabeth Rachlew; Stacey Sorensen; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; KTH thesis; synchrotron radiation; gas phase; bio molecules; Atomic and molecular physics; Atom- och molekylfysik;

    Sammanfattning : This thesis summarises experimental results on the molecular spectroscopy of gas phase molecules excited by synchrotron radiation in the VUV and soft X-ray regions. We have used three different detection techniques, photon induced fluorescence spectroscopy, photoionisation mass spectroscopy and near edge X-ray absorption fine structure spectroscopy to study molecular deuterium, hydrogen sulphide, ammonia, methanol, pyridine, pyridazine, pyrimidine, pyrazine, s-triazine, and 2-deoxy-D-ribose, the last one also known as the DNA sugar. LÄS MER

  7. 5. Fluorine-Free Ionic Liquid Based Electrolytes: Synthesis and Structural Characterization

    Författare :Mukhtiar Ahmed; Faiz Ullah Shah; Patrik Johansson; Jiayin Yuan; Luleå tekniska universitet; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Ionic Liquids; Electrolytes; Sustainability; Vitamin B3; Chemistry of Interfaces; Gränsytors kemi;

    Sammanfattning : Since their introduction by Sony in 1990, lithium-ion batteries (LIBs) have acquired a sizable market share. They have the best energy densities, a high open circuit voltage, a low self-discharge rate, no memory effect, and a slow loss of charge when not in use. LÄS MER