Sökning: "porphyrin"

Visar resultat 6 - 10 av 90 avhandlingar innehållade ordet porphyrin.

  1. 6. Crystallographic studies on porphyrin metallation by ferrochelatase

    Författare :David Lecerof; Biokemi och Strukturbiologi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; thermal and mechanical properties; Condensed matter:stucture; fasjämvikt; kristallografi; egenskaper termiska och mekaniska ; Kondenserade materiens egenskaper:struktur; crystallography; phase equilibria; Magnesium; pi-helix; Zinc; ferrochelatase; Metal binding; porphyrin metallation;

    Sammanfattning : Ferrochelatase catalyses the terminal step in heme biosynthesis by inserting a ferrous ion into protoporphyrin IX. The reaction mechanism has in this thesis been studied by mainly crystallographic methods. LÄS MER

  3. 7. Influence of Bridge Structures on the Electron Transfer in Donor-Acceptor Systems

    Författare :Mikael Winters; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; molecular wire; electron transfer; porphyrin; conjugated oligomer;

    Sammanfattning : In this Thesis, porphyrin-based donor-acceptor systems have been used to study photoinduced electron transfer processes. Principally, two different sets of systems have been investigated. LÄS MER

  4. 8. Synthesis of Covalently Linked Diporphyrins: Model Compounds for Intramolecular Energy and Electron Transfer

    Författare :Johan Kajanus; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; donor-bridge-acceptor systems; Sonogashira reaction; electron transfer; porphyrin; palladium; model compound; energy transfer;

    Sammanfattning : Three series of donor-bridge-acceptor compounds have been synthesized to probe the influence of various bridge chromophores on energy and electron transfer. The donor-bridge-acceptor compounds in each series comprise two different porphyrins, acting as donor and acceptor, covalently linked by bridge chromophores. LÄS MER

  5. 9. Ultrafast Dynamics in Ground and Excited States of Porphyrin Molecules

    Författare :Peter Martinsson; Kemisk fysik; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; intra- and intermolecular dynamics.; Zn-porphyrin; bacteriochlorophyll a; chlorophyll b; Femtosecond transient absorption spectroscopy; chlorophyll a; Physical chemistry; Fysikalisk kemi;

    Sammanfattning : This thesis describes inter and intramolecular dynamics in porphyrin molecules. To create a basis for understanding the energy and electron transfer processes in photosynthesis, the ultrafast dynamics of monomeric chlorophyll a, chlorophyll b and bacteriochlorophyll a were studied with ultrashort laser pulses. LÄS MER

  7. 10. Tuning of Energy and Electron Transfer Rates in Donor-Bridge-Acceptor Systems

    Författare :Karin Pettersson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; electron transfer; electronic coupling; paramagnetic species; superexchange; Donor-bridge-acceptor system; spectroscopy.; porphyrin; sequential electron transfer; Förster energy transfer; energy transfer;

    Sammanfattning : The intramolecular processes of Donor-Bridge-Acceptor (D-B-A) systems have been investigated by spectroscopic methods. The systems consist of porphyrin donors and acceptors linked by oligo-p-phenyleneethynylene bridges. LÄS MER