Sökning: "polymer chain length"

Visar resultat 21 - 25 av 68 avhandlingar innehållade orden polymer chain length.

1. 21. Amphiphilic Graft Copolymer Electrolytes for Lithium-Ion Polymer Batteries. - Preparation and Characterisation

   Författare :Patrik Gavelin; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polymer technology; biopolymers; Polymerteknik; Kemiteknik och kemisk teknologi; Chemical technology and engineering; transport dynamics; ion conductivity; solid polymer electrolyte; gel electrolyte; macromonomer copolymerization; amphiphilic graft copolymer;

   Sammanfattning : In the present work amphiphilic graft copolymers were prepared by free radical copolymerization of macromonomers in solution. The graft copolymers consisted of methacrylate backbones bearing ethylene oxide (EO)n side chains of varying length as ionophilic groups, and fluorocarbon (CF2)6 side chains or hydrocarbon groups as ionophobic groups. LÄS MER

3. 22. Microscopic Dynamics and Structure of some Polymer-based Electrolytes

   Författare :DANIEL ANDERSSON; Chalmers tekniska högskola; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; segmental motion; neutron scattering; ionic conduction; polymer electrolytes; gel electrolytes; Gaussianity; oligomers; photon correlation; PPO-LiClO4;

   Sammanfattning : The electrolyte is a key component in high-capacity lithium batteries and there is a large demand for improved materials to increase the performance. Polymer-based electrolytes offer advantages in the design of safer and lighter batteries. LÄS MER

4. 23. Thermal Isomerization of Azobenzene Side Chain Copolymers

   Författare :Viktoria Skeppstedt; Chalmers tekniska högskola; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; free volume; thermal isomerization; positron annihilation lifetime spectroscopy; physical ageing; phthalate; methyl methacrylate polymer; azo polymers; plasticization;

   Sammanfattning : Irradiation of azobenzene induces isomerization between its trans- and cis forms. By introduction of azobenzene chromophores in polymers, it is possible to optically control a variety of polymer properties. The isomerization of azobenzene can be used to influence conformational, optical or surface properties of the poly mer material. LÄS MER

5. 24. Glass Transition Dynamics in Soft Condensed Matter

   Författare :Johan Mattsson; Chalmers tekniska högskola; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; polymer films; beta relaxation; hydrogen bond; glass transition; polymer dynamics; cooperativity; confinement; IXS; Brillouin light scattering; excess wing;

   Sammanfattning : Materials of very different character, ranging from polymers to metals can be made into glasses. The structural and dynamical properties of glass-forming materials are fundamentally different from those found in crystals. Hence, glassy materials exhibit unique characteristics, which make them suitable for a wide range of applications. LÄS MER

7. 25. Mixed Block Copolymer Solutions: Self-Assembly and Interactions

   Författare :Solmaz Bayati; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polymer; Block Copolymer; PEO-PPO-PEO; Pluronics©; Bile Salt; NaGDC; PNIPAAM; PAMPTMA; PAMPS; Mixed Micelle; Self-Assembly; Mixed Complexes;

   Sammanfattning : This thesis incorporates studies on the aqueous systems of two types of thermoresponsive amphiphilic block copolymers; a series of nonionic triblock copolymers comprising blocks of poly(ethylene oxide) (PEO) and poly(propylene oxide) (PPO) denoted as PEO-PPO-PEO block copolymers, and a series of ionic diblock copolymers consisting of one charged block and one block of poly(N-isopropylacrylamide) (PNIPAAM). Various techniques, such as dynamic and static light scattering (DLS and SLS), small angle X-ray and neutron scattering (SAXS and SANS), high sensitivity differential scanning calorimetry (HSDSC), turbidimetry, electrophoretic mobility measurements, and two-dimensional proton NMR nuclear Overhauser effect spectroscopy (2D 1H NMR NOESY), were applied to study these block copolymer systems. LÄS MER