Sökning: "polyion"

Visar resultat 1 - 5 av 10 avhandlingar innehållade ordet polyion.

1. 1. Charged Polymers at Spherical Surfaces

   Författare :Anna Akinchina; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Fysikalisk kemi; Physical chemistry; Monte Carlo simulation; diblock polyampholyte brushes; polymer brushes; persistent length; stiffness; complexation; macroion; polyelectrolyte; polyion;

   Sammanfattning : Two separate topics in the area of colloidal chemistry have been investigated by the use of molecular modeling: the structural properties of polyion?macroion complexes and of diblock polyampholyte brushes. The main results were obtained by the use of Monte Carlo simulation in the framework of the primitive model, and in the case of polyampholyte brushes the simulation results were also complemented by lattice mean-field calculations. LÄS MER

3. 2. Interfacial Properties of Biomacromolecular Model Systems: Surface Forces and Nanotribology

   Författare :Niklas Nordgren; Mark Rutland; Harry Brumer III; Robert Pelton; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; afm; surface force; friction; composite material; model surface; quartz crystal microbalance; dissipation; cellulose; xyloglucan; chitosan; colloidal probe; nanotribology; biomimetic; enzymatic; polysaccharide; graft; fiber; thiol; spring constant; calibration; lubrication; polyion; responsive.; Surface and colloid chemistry; Yt- och kolloidkemi;

   Sammanfattning : The nanotribology, adhesion and related interfacial properties of biomacromolecular systems have been studied.  The aim was to elucidate the role of physisorbed and chemically grafted bio-polymers implicated as mediators for cellulose based processing and material design. LÄS MER

4. 3. Environmentally Responsive Surface Coatings of Polyion-Surfactant Ion Complex Salts

   Författare :Charlotte Gustavsson; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polymer; polyelectrolyte; surfactant; complex salt; surface coatings; phase behaviour; responsivness; hydration; SAXS; water-insoluble; solutes; liquid crystalline structures;

   Sammanfattning : Complexes formed between oppositely charged polyions and surfactant ions are known to have very rich phase behaviour in bulk solution. The work in this thesis investigates the possibilites of using such complexes as surface coatings. LÄS MER

5. 4. Phase Behavior and Solution Properties of Aqueous Polyion-Surfactant Ion Systems

   Författare :John Janiak; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polymer-surfactant association; complex salt; nonionic surfactant; poly acrylic acid ; poly methacrylic acid ; copolymer; polymeric counterion; decyl betainate; phase behavior; solubilization; mixed micelle; hydrolysis; release; liquid crystal; nanoparticles; thermosresponsive; C12E8; C12E5;

   Sammanfattning : Polyelectrolytes and oppositely charged surfactants interact through attractive electrostatic forces, which in many cases lead to phase separation already at low total concentrations. During the past 10-15 years investigations of these systems have been simplified through the use of complex salts that consist of surfactants with polymeric counterions in a 1:1 charge stoichiometry (no excess simple counterions present). LÄS MER

7. 5. Controlling Structure and Water Miscibility of Polyion - Surfactant Ion Complex Salts

   Författare :Jens Norrman; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Physical chemistry; Fysikalisk kemi; phase diagram; cubic Pm3n; hexagonal; lamellar; self diffusion; PFG NMR; SAXS; liquid crystals; polymer; counterion; complex; polyelectrolyte; surfactant;

   Sammanfattning : The interaction between poylions and oppositely charged surfactant ions has been investigated. This has been done by using the pure complex salt (polyion + surfactant ion) as a point of departure. Different parameters of the complex salt have been varied in a systematic way and the effect on structure and water miscibility has been investigated. LÄS MER