Sökning: "polyelectrolyte"

Visar resultat 21 - 25 av 132 avhandlingar innehållade ordet polyelectrolyte.

1. 21. Charged Polymers at Spherical Surfaces

   Författare :Anna Akinchina; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Fysikalisk kemi; Physical chemistry; Monte Carlo simulation; diblock polyampholyte brushes; polymer brushes; persistent length; stiffness; complexation; macroion; polyelectrolyte; polyion;

   Sammanfattning : Two separate topics in the area of colloidal chemistry have been investigated by the use of molecular modeling: the structural properties of polyion?macroion complexes and of diblock polyampholyte brushes. The main results were obtained by the use of Monte Carlo simulation in the framework of the primitive model, and in the case of polyampholyte brushes the simulation results were also complemented by lattice mean-field calculations. LÄS MER

3. 22. Association Phenomena Involving Hydrophobically Modified Polymers. Electrostatic and Hydrophobic Contributions

   Författare :Marina Tsianou; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; scaling; light scattering; rheology; aqueous solution behavior; phase behavior; cyclodextrin; surfactant; polyacrylate; cellulose ether; polyelectrolyte; hydrophobically modified polymer; Polymer; water soluble polymer; viscosity; association; segregation; Physical chemistry; Fysikalisk kemi;

   Sammanfattning : The electrostatic and hydrophobic interactions in aqueous solutions of hydrophobically-modified water-soluble non-ionic or ionic polymers, their mixtures with a second polymer, nonionic or of opposite charge, and their mixtures with surfactants of opposite charge have been investigated. The relative strength of the electrostatic and hydrophobic contributions has been modulated by a variation of the polymer charge density and the solution pH, and by a variation in the degree and strength of the hydrophobic modifications, respectively. LÄS MER

4. 23. Interactions of Anticancer Active Platinum(II) Complexes with DNA

   Författare :Johan Kjellström; Bröstcancer-genetik; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Inorganic chemistry; polyelectrolyte; medium effects; salt dependence; DSC; CD; HPLC; oligonucleotide; hairpin; DNA; anticancer active platinum II compounds; kinetics; mechanism; Oorganisk kemi; Cytology; oncology; cancerology; Cytologi; onkologi; cancer;

   Sammanfattning : The kinetics and mechanism for interactions of the anticancer active platinum(II) complexes cis-[PtCl2(NH3)2)], cis-[PtCl2(NH3)(c-C6H11NH2)], and trans-[PtCl2-(NH3)(quinoline)] with DNA have been studied using a combination of HPLC, circular dichroism (CD), UV/vis spectroscopy, and differential scanning calorimetry (DSC). Reactions of the monoaqua forms (charge = +1) of these complexes with single-stranded DNA oligonucleotides, typically between 13-17 bases long, were found to depend on i) the composition of the reaction medium, ii) the exact nature and location of the platination target, and iii) on the DNA structure. LÄS MER

5. 24. Theoretical and Experimental Studies of Polymer Adsorption and Polymer Mediated Interactions

   Författare :Fei Xie; Beräkningskemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polyelectrolyte; Adsorption; Colloid; Polymer; Dispersion; Interation; Ellipsometry; Monte Carlo Simulation; Classical Density Functional Theory;

   Sammanfattning : Polyelectrolyte adsorption and polymer mediated interactions in different colloidal polymer systems have been studied in this work. Theoretical methods and experimental techniques are combined, in order to obtain more general reliable results, as well as a deep understanding of the molecular mechanisms that are responsible for the observed behaviors. LÄS MER

7. 25. Self assembly of surfactants and polyelectrolytes in solution and at interfaces

   Författare :Luis Alejandro Bastardo Zambrano; Per Claesson; Jan Skov Pedersen; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Surfactant; polyelectrolyte; small–angle neutron scattering; static light scattering; dynamic light scattering; polyelectrolyte–surfactant association; protein; Surface and colloid chemistry; Yt- och kolloidkemi;

   Sammanfattning : This thesis focuses on the study of the interactions between polyelectrolytes and surfactants in aqueous solutions and at interfaces, as well as on the structural changes these molecules undergo due to that interaction. Small–angle neutron scattering, dynamic, and static light scattering were the main techniques used to investigate the interactions in bulk. LÄS MER