Sökning: "polyelectrolyte"

Visar resultat 11 - 15 av 132 avhandlingar innehållade ordet polyelectrolyte.

  1. 11. Structure-Property Relationships of Surfactants at Interfaces and Polyelectrolyte-Surfactant Aggregates

    Författare :Mikael Kjellin; KTH; []
    Nyckelord :nonionic surfactant; sugar surfactant; poly ethylene oxide ; amide; ester; polyelectrolyte; SDS; hydrophobic surface; glass surface; mica; adsorption; aggregation; micelle size; surface forces; wetting; dynamic surface tension; NMR; TRFQ; SANS; SAXS; ;

    Sammanfattning : The first part of this thesis is concerned with thestructure-property relationships in nonionic surfactantsystems. The main aim was to investigate how the surfactantstructure influences the adsorption at interfaces andinteractions between surfactant coated interfaces. LÄS MER

  3. 12. Appropriate conditions for polyelectrolyte titration to determine the charge of cellulosic fibers

    Författare :Elisabet Horvath; KTH; []
    Nyckelord :adsorption; electrolyte; polyelectrolyte; ;

    Sammanfattning : The polyelectrolyte titration method has been developed overthe years in order to determine the surface charge ofcellulosic fibers. The conditions have been varied depending onthe author. LÄS MER

  4. 13. Polyelectrolyte - Surfactant Interactions in Dilute Suspensions. A Study Based on Monte Carlo simulations and Mean-Field Calcultations

    Författare :Torsten Wallin; Fysikalisk kemi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; aggregation number; linear charge density; chain flexibility; mean-field; calculation; simulation; Monte Carlo; cmc; cac; interaction; electrostatic; charged; micelle; polyelectrolyte; surfactant; hydrophilic; hydrophobic; Physical chemistry; Fysikalisk kemi;

    Sammanfattning : The complexation of macroions or charged micelles and oppositely charged polyelectrolytes was studied by the use of Monte-Carlo simulations and mean field calculations. The Monte-Carlo simulations were performed on a simple model system with the emphasis on the electrostatic interaction, (i) polyelectrolyte rigidity, (ii) polyelectrolyte linear charge density, (iii) surfactant tail length, and (iv) the polyelectrolyte concentration. LÄS MER

  5. 14. Phase Phenomena in Polymer Networks : Empirical Studies on the Influence of Hydrophobicity, Charge Density and Crosslinks on Macroion-Induced Phase Transitions in Polyelectrolyte Gels

    Författare :Martin Andersson; Per Hansson; Lennart Piculell; Uppsala universitet; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Gel; microgel; microsphere; polystyrenesulfonate; polyacrylate; polyacrylicacid; DoTAB; DoTAC; CTAB; CTAC; network; polyelectrolyte; complex salt; self assembly; phase behaviour; hysteresis; thermodynamic; core-shell; lysozyme; cytochrome c; microscopy; micromanipulator; elastomer; elastic; protein; surfactant; phase behaviour; sorting; PHARMACY; FARMACI; Physical chemistry; Fysikalisk kemi;

    Sammanfattning : The thesis concerns polyelectrolyte gels in contact with oppositely charged proteins and surfactant micelles, and includes of four papers (I-IV). In paper I confocal Raman spectroscopy was introduced as a method to trace micelles and investigate the structure of gel-surfactant complexes, in phase separated gel spheres. LÄS MER

  7. 15. Polyelectrolyte Brush Electrodes for Protein Capture and Release

    Författare :Gustav Ferrand-Drake Del Castillo; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; pH-responsive interfaces; Polyelectrolyte brushes; protein immobilization; electrochemistry.;

    Sammanfattning : Stimuli-responsive polyelectrolyte brushes switch as a function of pH between a charged and neutral state that affects their electrostatic interactions with other charged molecules like proteins. Adjustment of the pH results in the binding of large quantities of proteins making polyelectrolyte brushes widely used as biointerfaces. LÄS MER