Sökning: "physical chemistry"

Visar resultat 21 - 25 av 1501 avhandlingar innehållade orden physical chemistry.

  1. 21. Atomic Scale Degradation of Zirconium Alloys for Nuclear Applications

    Författare :Gustav Sundell; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Irradiation damage; Hydrogen microanalysis; Hydrogen pick-up; Zirconium alloys; Atom probe tomography; Corrosion;

    Sammanfattning : Due to their low thermal neutron capture cross-section, zirconium alloys are widely used in the nuclear industry as fuel cladding and for structural components. The lifetime of the fuel assemblies in the reactors is primarily dictated by the ability of the cladding to withstand oxidation and hydrogen pick-up from the coolant water and radiation damage induced by the neutron flux. LÄS MER

  2. 22. Unravelling Sensitisation and Quenching Pathways in Lanthanide Luminophores

    Författare :Salauat Kiraev; Eszter Borbas; Thomas Just Sørensen; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Lanthanide; Luminescence; Sensitisation; Quenching; Energy Transfer; Electron transfer; Kemi; Chemistry;

    Sammanfattning : Lanthanide (Ln) ions find use in cellular detection and probing of many analytes, owing to their unique photophysical properties. However, to make the Ln emission efficient, one has to develop a light-harvesting antenna, which is an organic chromophore that absorbs and transfers energy to the Ln. LÄS MER

  3. 23. Kinetic Measurements Using Nanoplasmonic Sensing

    Författare :Markus Schwind; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Sn Nanoparticles; Sensing; Localized Surface Plasmon Resonances; Particle Plasmon; Metal Oxidation; Metal Corrosion; Solid-Liquid Phase Transition; Kinetics; Al Nanoparticles;

    Sammanfattning : In this thesis the nanoplasmonic sensing technique was used to study kinetics of (i) the oxidation of Al nanoparticles in air and water and (ii) the solid-liquid phase transition in Sn nanoparticles. The nanoplasmonic sensing technique detects changes of the localized surface plasmon resonance (LSPR) in metal nanoparticles. LÄS MER

  4. 24. Modification of microcapsules for controlled release

    Författare :Markus Andersson Trojer; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; block copolymer; coordination chemistry; polyelectrolyte multilayer; cross-linking; vibrational spectroscopy; electron paramagnetic resonance; imidazole; controlled release; colloidal stability; Microcapsule; quartz crystal microbalance with dissipation;

    Sammanfattning : Fouling of marine organisms such as algae and barnacles on the boat hull is an enormous problem for the shipping industry. The negative consequences for the society are both economical and environmental. To prevent fouling in general, biocides are typically incorporated directly into the paint. LÄS MER

  5. 25. Investigating polymorphism in small molecules using three-dimensional electron diffraction

    Författare :Molly Lightowler; Xiaodong Zou; Hosea M. Nelson; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; 3D electron diffraction; structure determination; polymorphism; crystallisation; phase identification; small molecule; oorganisk kemi; Inorganic Chemistry;

    Sammanfattning : For scientific, regulatory and intellectual property reasons, the discovery and characterisation of polymorphic systems is an integral aspect of the development process of any solid-formulated drug product. Yet, these studies are often hindered by crystal quality and size, poor yields and the generation of mixtures of phases. LÄS MER