Sökning: "phosphines"

Visar resultat 16 - 19 av 19 avhandlingar innehållade ordet phosphines.

  1. 16. The chemistry of organic iodides under severe nuclear accident conditions in LWRs

    Författare :Sabrina Tietze; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic iodides; Wet-filter system scrubber ; Chlorine; Volatile iodine source term; Severe nuclear accident; Cables; Sorption; Containment; Paint; Iodine; LWR; Radiolysis;

    Sammanfattning : For many countries nuclear fission is an important part of their energy portfolio. However, a great concern is the occurrence of nuclear reactor accidents, which can result in the emission of radioactivity into the environment. LÄS MER

  3. 17. Molecular Motion in Frustrated Lewis Pair Chemistry: insights from modelling

    Författare :Maoping Pu; Timofei Privalov; Todd Martinez; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; CO2 capture; hydrogen activation; molecular motion; ab initio molecular dynamics; frustrated Lewis pair; quantum chemical modelling; reaction mechanism; Organic Chemistry; organisk kemi;

    Sammanfattning : Mechanisms of reactions of the frustrated Lewis pairs (FLPs) with carbon dioxide (CO2) and hydrogen (H2) are studied by using quantum chemical modelling. FLPs are relatively novel chemical systems in which steric effects prevent a Lewis base (LB) from donating its electron pair to a Lewis acid (LA). LÄS MER

  4. 18. Asymmetric Hydrogenations of Imines, Vinyl Fluorides, Enol Phosphinates and Other Alkenes Using N,P-Ligated Iridium Complexes

    Författare :Jarle Sidney Diesen; Pher G. Andersson; Kálmán J. Szabó; Uppsala universitet; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Organic chemistry; Catalysis; Asymmetric; Hydrogenations; Reductions; Alkenes; Imines; Vinyl fluorides; Enolphosphinates; Transition metal; Complexes; Iridium; Organisk kemi; Chemistry; Kemi;

    Sammanfattning : The research described in this thesis is directed toward the efficient, enantioselective synthesis of chiral products that have useful functionality. This goal was pursued through catalytic asymmetric hydrogenation, a reaction class that selectively introduces one or two stereocenters into a molecule in an atom-efficient step. LÄS MER

  5. 19. Metallacyclic Phosphine Complexes and Intramolecular Csp3-H Bond Activation -Synthesis, Characterisation and Catalytic Application

    Författare :Sven Sjövall; Kemiska institutionen; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; catalysis; Heck; diphosphite; diphosphine; phosphine; cyclometallation; C-C activation; C-O activation; C-H activation; palladium; rhodium; iridium; Inorganic chemistry; Oorganisk kemi;

    Sammanfattning : The work presented in this thesis deals with metallacyclic late transition metal complexes, obtained by intramolecular Csp3-H activation, and the application of such compounds in catalysis. The new hemilabile P,O phosphines N-methyl-N-propionyl-2-(diphenylphosphino)benzylamine (DPPAM), o-(diphenylphosphino)benzoic acid ethyl ester (DPPES), o-(diphenylphosphino)benzoic acid methyl ether (DPPET) and ±-1-(2- diphenylphosphino)phenylethyl propionate (±-DPPMES) and the symmetrical diphosphorus donor ligands cis-1,3-bis[(diphenylphosphino)methyl]-cyclohexane (DPCY), cis-1,3-bis[(di-tertbutylphosphino)methyl]cyclohexane (DTBCY) and cis-1,3-bis[(di-isopropylphosphino)methyl]cyclohexane (DIPCY) have been synthesised, allowing the preparation of a range of new metallacyclic rhodium(III), iridium(III) and palladium(II) complexes. LÄS MER