Sökning: "phosphine-substitution"

Hittade 1 avhandling innehållade ordet phosphine-substitution.

  1. 1. Iron Carbonyl Clusters as Proton Reduction Catalysts

    Författare :Ahibur Rahaman; Kemisk fysik; []
    Nyckelord :iron-only hydrogenase; phosphine-substitution; electrocatalysis; proton reduction;

    Sammanfattning : Abstract – The mixed-valence triiron complexes [Fe3(CO)7-x(PPh3)x(µ-edt)2] (x = 0, 1, 2; edt = SCH2CH2S) and [Fe3(CO)5(κ2-diphosphine)(µ-edt)2] (diphosphine = dppv, dppe, dppb, dppn) have been prepared and structurally characterized. In comparison to the diiron complex [Fe2(CO)6(µ-edt)], [Fe3(CO)7(µ-edt)2] catalyzes proton reduction at 0. LÄS MER