Sökning: "phase association"
Visar resultat 1 - 5 av 243 avhandlingar innehållade orden phase association.
1. Association Phenomena Involving Hydrophobically Modified Polymers. Electrostatic and Hydrophobic Contributions
Sammanfattning : The electrostatic and hydrophobic interactions in aqueous solutions of hydrophobically-modified water-soluble non-ionic or ionic polymers, their mixtures with a second polymer, nonionic or of opposite charge, and their mixtures with surfactants of opposite charge have been investigated. The relative strength of the electrostatic and hydrophobic contributions has been modulated by a variation of the polymer charge density and the solution pH, and by a variation in the degree and strength of the hydrophobic modifications, respectively. LÄS MER
2. Solution properties of a hydrophobically modified polymer
Sammanfattning : The influence of hydrophobic modification on solution properties of water-soluble polymers in the semi-dilute regime have been studied. The nonionic ethyl(hydroxyethyl)cellulose (EHEC) and its hydrophobically modified analogue (HM-EHEC) are used as model substances. LÄS MER
3. Phase Behavior and Solution Properties of Aqueous Polyion-Surfactant Ion Systems
Sammanfattning : Polyelectrolytes and oppositely charged surfactants interact through attractive electrostatic forces, which in many cases lead to phase separation already at low total concentrations. During the past 10-15 years investigations of these systems have been simplified through the use of complex salts that consist of surfactants with polymeric counterions in a 1:1 charge stoichiometry (no excess simple counterions present). LÄS MER
4. Characterisation of Aqueous Solutions, Liquid Crystals and Solid State of Non-ionic Polymers in Association with Amphiphiles and Drugs
Sammanfattning : Cellulose ethers and polyethylene glycols are used in drug formulations as water swelling or water soluble matrices. Polar lipids, for example monoglycerides, and surfactants can be used to solubilise hydrophobic or amphiphilic drugs and to formulate potential drug delivery vehicles such as emulsions, liposomes and cubic phases. LÄS MER
5. Molecular Association Studied by NMR Spectroscopy
Sammanfattning : This Thesis presents studies of molecular association in aqueous solution and at the liquid/solid interface. The investigated molecular systems range from self-aggregating surfactants to hydration water in contact with micelles or individual molecules. In most studies, combinations of various NMR methods were applied. LÄS MER