Sökning: "partial oxidation"

Visar resultat 1 - 5 av 92 avhandlingar innehållade orden partial oxidation.

  1. 1. Partial methane oxidation from electronic structure calculations

    Författare :Adam Arvidsson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; ZSM-5 zeolite; density functional theory; microkinetic modelling; Mo6S8 cluster; partial methane oxidation;

    Sammanfattning : Investigating catalytic reactions with computational methods is a powerful approach to understand fundamental aspects of catalytic reactions and find ways to guide catalytic design. Partial methane oxidation is one example of a reaction with intriguing challenges, where a detailed atomistic approach may help to unravel the bottlenecks of this, as of yet, inefficient reaction. LÄS MER

  3. 2. Selective oxidation over mixed oxide catalysts

    Författare :Robert Häggblad; Avdelningen för kemiteknik; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; propane; catalysis; Selective oxidation; transition metal oxides; vanadium; molybdenum; methanol oxidation; ammoxidation; propene; acrylonitrile; formaldehyde;

    Sammanfattning : Since the metal oxide catalysts used in many chemical processes show very high selectivity for the products aimed at, both today and in the future, they play a key role in the environmentally and economically sustainable production of chemical intermediates. Two processes of this sort have been studied in the thesis: the ammoxidation of propane and propene over a Mo-V-Nb-Te-oxide catalyst and the selective oxidation of methanol over vanadium-based catalysts. LÄS MER

  4. 3. Partial methane oxidation: insights from first principles and micro-kinetics calculations

    Författare :Adam Arvidsson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; zeolite acidity; zeolites; density functional theory; microkinetic modelling; molybdenum sulfide cluster; partial methane oxidation;

    Sammanfattning : Partial methane oxidation is a much-desired reaction with some intriguing challenges. Not only is there a need to activate methane and oxygen, but there is also a need to control the selectivity and prevent over-oxidation to thermodynamically more stable products, like carbon dioxide and water. LÄS MER

  5. 4. Sulfur Capture and Oxidation of Calcium Sulfide in PFBC

    Författare :Kuanrong Qiu; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; oxidation; model; pressure; sulfur; PFBC; CaS; limestone; CaSO4; PTGA; regeneration;

    Sammanfattning : Sorbents such as limestone are successfully used for removal of SO2 during pressurized fluidized bed combustion (PFBC) processes. However, there still remains a strong incentive to reduce the consumption of such sorbents. LÄS MER

  7. 5. Investigations on the Oxidation of Iron-chromium and Iron-vanadium Molten Alloys

    Författare :Haijuan Wang; Seshadri Seetharaman; Ashok Lahiri; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Oxidation; High-alloy steelmaking; Retention; CO2-O2; Fe-Cr melt; Fe-Cr-C melt; Fe-V melt; Vanadium containing slags; Kinetics; Thermodynamics properties.; Metallurgical process engineering; Metallurgisk processteknik; Materials science; Teknisk materialvetenskap;

    Sammanfattning : With the progress of high alloy steelmaking processes, it is essential to minimize the loss of valuable metals, like chromium and vanadium during the decarburization process, from both economic as well as environmental view points. One unique technique to realize this aim, used in the present work, is the decarburization of high alloy steel grades using oxygen with CO2 in order to reduce the partial pressure of oxygen. LÄS MER