Sökning: "palladium IV"
Visar resultat 1 - 5 av 41 avhandlingar innehållade orden palladium IV.
1. Structural Properties of Palladium-Manganese Alloys
Sammanfattning : Structural properties of adsorbed overlayers on well-defined single crystals and of Palladium-Manganese surface alloys formed on Pd(100) have been investigated using synchrotron-based photoemission, scanning tunneling microscopy and Fourier-transform infrared spectroscopy. The experimental valence electronic structure of PdMn systems on Pd(100) is compared to density functional calculations (DFT). LÄS MER
2. Novel Pincer Complex-Catalyzed Transformations : Including Asymmetric Catalysis
Sammanfattning : This thesis is focused on the development of new pincer complex-catalyzed transformations. Optimization of the catalytic properties (fine-tuning) was directed to increase the catalytic activity as well as the chemo-, stereo- and enantioselectivity of the complexes. LÄS MER
3. Structure-Reactivity Correlations for Reactions of Palladium(II) and Platinum(IV) Complexes
Sammanfattning : The kinetics and mechanism for substitution reactions on tetraaquapalladium(II) by an extended series of thioethers, a great number of carboxylic acids, and olefins have been studied by use of UV-VIS, stopped-flow, and high-pressure stopped-flow spectrophotometry and NMR spectroscopy. Second-order rate constants k and activation parameters (activation enthalpies, entropies, and volumes) for formation of monodentate 1:1 complexes have been determined. LÄS MER
4. Exploring Palladium-Mediated 11C/12C-Carbonylation Reactions : PET Tracer Development Targeting the Vesicular Acetylcholine Transporter
Sammanfattning : The work presented herein describes the utilization and exploration of palladium-mediated incorporations of carbon monoxide and/or [11C]carbon monoxide into compounds and structural motifs with biological relevance.The first part of the thesis describes the design, synthesis and 11C-labeling of prospective PET tracers for the vesicular acetylcholine transporter (VAChT), a target affected in several neurodegenerative diseases. LÄS MER
5. Catalytic and Electrocatalytic Transformations with Palladium and Nickel : Scope and mechanistic investigations
Sammanfattning : The work presented in this thesis is based on methodology development and mechanistic investigations using heterogeneous palladium and nickel catalysts. Following the introduction (Chapter 1), Chapter 2 presents a summary of the synthesis and characterization of the MOF-supported Pd catalysts (Pd @ MOF) that are used in this thesis. LÄS MER
