Sökning: "oxidants"

Visar resultat 11 - 15 av 83 avhandlingar innehållade ordet oxidants.

  1. 11. Physical and Chemical Aspects of Radiation Induced Oxidative Dissolution of UO2

    Författare :Olivia Roth; Mats Jonsson; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; UO2; spent nuclear fuel; dissolution; oxidation; radiolysis; irradiation; particle size; modeling; Chemistry; Kemi;

    Sammanfattning : Denna licensiatavhandling behandlar oxidativ upplösning av UO2. Upplösning av UO2 studeras huvudsakligen då UO2-matrisen hos använt kärnbränsle förväntas fungera som en barriär mot frigörande av radionuklider i ett framtida djupförvar. LÄS MER

  3. 12. Kinetics for oxidation of CRUD model compounds

    Författare :Maryam Abili Nejad; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; reactor chemistry; radiolysis; oxidation; kinetics; crud; metal oxide;

    Sammanfattning : The formation of CRUD (Chalk River Unidentified Deposit) inwater-cooled nuclear reactors constitute a severe problem. Thestability of CRUD under reactor conditions (high flux ofionizing radition, high temperature and pressure) must be knownin order to minimize the problem. LÄS MER

  4. 13. Palladium-catalyzed C-H functionalization of alkenes under oxidative conditions

    Författare :Johanna M Larsson; Kálmán Szabó; Eszter Borbas; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Organisk kemi;

    Sammanfattning : The unique properties of high oxidation state palladium have been used to develop new catalytic alkene C-H functionalization reactions. A Heck-type coupling based on the reactivity of palladium catalysts and diaryliodonium salts has been developed with broad synthetic scope and tolerance for functional groups that are ordinarily reactive in Pd0/PdII catalysis, for example, allylic acetates and aryl bromides. LÄS MER

  5. 14. In vitro and in vivo oxidation of diastereomers of lignin models of arylgylcerol b-aryl ether type and heterologous expression of laccase

    Författare :Christina Bohlin; Leif Jönsson; Ming Tien; Karlstads universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Biochemistry; Biokemi; Kemi; Chemistry;

    Sammanfattning : Enzymic and non-enzymic oxidation of lignin models of the arylglycerol β-aryl ether type was investigated in experiments aimed at providing a better understanding of the initial phase of biological lignin degradation. Product profiles and diasteromer selectivity were determined to gain knowledge of the properties of the oxidants and pave the way for evaluation of the presence of the oxidants in ligninolytic fungal cultures. LÄS MER

  7. 15. Measurement of Self-Heating of Biomass Pellets using Isothermal Calorimetry

    Författare :Ida Larsson; Karin Granström; Anders Lönnermark; Per Blomqvist; Patrick van Hees; Karlstads universitet; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; isothermal calorimetry; biomass pellets; wood pellets; self-heating; reactivity; screening test; isoterm kalorimetri; pellets; biomassa; självuppvärmning; reaktivitet; screeningtest; Miljö- och energisystem; Environmental and Energy Systems;

    Sammanfattning : Self-heating in storage facilities of biomass pellet can lead to spontaneous combustion. This has resulted in many fires over the years, causing both financial and environmental losses.In order to assess the risk for spontaneous combustion of biomass pellets during storage, it is important to know how prone the fuel is to self-heating, i.e. LÄS MER