Sökning: "outer-sphere"

Visar resultat 1 - 5 av 14 avhandlingar innehållade ordet outer-sphere.

  1. 1. Mechanistic Studies on Ruthenium-Catalyzed Hydrogen Transfer Reactions

    Författare :Jenny B. Åberg; Jan-Erling Bäckvall; Charles P. Casey; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; mechanistic studies; catalysis; ruthenium; hydrogen transfer; racemization; transfer hydrogenation; alcohols; ketones; amines; imines; inner-sphere; outer-sphere; solvent cage effect; Organic chemistry; Organisk kemi; organisk kemi; Organic Chemistry;

    Sammanfattning : Mechanistic studies on three different ruthenium-based catalysts have been performed. The catalysts have in common that they have been employed in hydrogen transfer reactions involving alcohols and ketones, amines and imines or both. LÄS MER

  3. 2. Solubility and Surface Complexation Studies of Apatites

    Författare :Åsa Bengtsson; Staffan Sjöberg; Per Persson; Lars Lövgren; Laurent Charlet; Umeå universitet; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; apatite; dissolution; calcium; phosphate; fluoride; goethite; surface complexation; speciation; outer-sphere complexation; FTIR; XPS; potentiometry; Chemistry; Kemi;

    Sammanfattning : Apatites are a diverse class of phosphate minerals that are important in a great variety of natural and industrial processes. They are, for example, used as raw material in fertiliser production and in the remediation of metal-contaminated soils. LÄS MER

  4. 3. Coordination Chemistry of Monocarboxylate and Aminocarboxylate Complexes at the Water/Goethite Interface

    Författare :Katarina Norén; Per Persson; Staffan Sjöberg; Stephan J. Hug; Umeå universitet; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Acetate; benzoate; adsorption; surface complex; ternary surface complexes; ATR-FTIR spectroscopy; EXAFS spectroscopy.; cyclohexanecarboxylate; sarcosine; MIDA; EDDA; EDTA; gallium III ; goethite; mineral surface; Chemistry; Kemi;

    Sammanfattning : This thesis is a summary of five papers with focus on adsorption processes of various monocarboxylates and aminocarboxylates at the water/goethite interface. Interaction of organic acids at the water/mineral interfaces are of importance in biogeochemical processes, since such processes have potential to alter mobility and bioavailability of the acids and metal ions. LÄS MER

  5. 4. Selective transfer hydrogenations : Catalyst development and mechanistic investigations

    Författare :Jenny Wettergren; Hans Adolfsson; Serafino Gladiali; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; asymmetric catalysis; transfer hydrogenation; transition metal; amino acids; amino alcohols; Organic chemistry; Organisk kemi; Organic Chemistry; organisk kemi;

    Sammanfattning : By generating a library of amino acid-based ligands, pseudo-dipeptides, and combining them with transition metals, we have created selective and efficient ruthenium and rhodium catalysts for the asymmetric transfer hydrogenation of ketones. The ruthenium-catalyzed reaction was studied in detail, and we found that alkali metals play a crucial role for the reactivity and selectivity of the reaction. LÄS MER

  7. 5. Spectroscopic studies of solvation and adsorption properties of PVP

    Författare :Ildikó Száraz; Luleå tekniska universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Chemistry of Interfaces; Gränsytors kemi;

    Sammanfattning : The adsorption mechanism of 1-vinyl-2-pyrrolidone (VP), poly(1-vinyl-2- pyrrolidone) (PVP) and azelaic acid on synthetic gamma-aluminium oxide surfaces was investigated using FT-IR, FT-Raman, UV, 1H and 13C NMR spectroscopy. (Liquid-solid state) As a first step the solvation of VP and PVP in solvents of varying polarity, specifically water, ethylene glycol (EG), chloroform and carbon tetrachloride, was studied. LÄS MER