Sökning: "osmium redox polymer"

Hittade 5 avhandlingar innehållade orden osmium redox polymer.

  1. 1. Conducting Polymers Containing In-Chain Metal Centres : Electropolymerisation and Charge Transport

    Författare :Johan Hjelm; Anders Hagfeldt; Emad Mukhtar; Robert Forster; A. R. Hillman; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Physical chemistry; Polymer electrochemistry; Conducting Polymers; Metal Complexes; Electropolymerization; Electron-hopping; Microelectrodes; Fysikalisk kemi; Physical chemistry; Fysikalisk kemi; Physical Chemistry; fysikalisk kemi;

    Sammanfattning : Conjugated polymers that exhibit high electronic conductivities play key roles in the emerging field of molecular electronics. In particular, linking metal centres with useful electrochemical, photophysical, or catalytic properties to the backbone, or within the polymer chain itself, is a topic which has attracted a significant amount of interest lately. LÄS MER

  3. 2. Extracellular electron transfer features of the Gram-positive bacterium Enterococcus faecalis

    Författare :Galina Pankratova; Biokemi och Strukturbiologi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Gram-positive bacteria; Enterococcus faecalis; Extracellular electron transfer; Electron-conducting redox polymers; Mediated electron transfer;

    Sammanfattning : Electroactive microorganisms possess the unique ability to transfer electrons to or from a solid phase electron conductor, e.g., electrodes or minerals, through various physiological mechanisms. LÄS MER

  4. 3. 2nd and 3rd generation electrodes for biosensors and biofuel cells

    Författare :MNadeem Zafar; Biokemi och Strukturbiologi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; WrbA; pyranose dehydrogenase; cellobiose dehydrogenase; glucose dehydrogenase; direct electron transfer; Os-polymers; mediated electron transfer; single-walled carbon nanotubes; amperometric biosensor; biofuel cell; screen-printed electrodes; flow injection analysis; cascade reaction; bioanode;

    Sammanfattning : The catalytic and electrochemical properties of tryptophan repressor-binding protein (WrbA), pyranose dehydrogenase (PDH), cellobiose dehydrogenase (CDH) and glucose dehydrogenase (GDH) on carbon electrodes were investigated using cyclic voltammetry and flow injection amperometry to construct biosensors and biofuel cell (BFC) anodes. WrbA has a catalytic FMN-containing domain whereas both PDH and GDH have a catalytic FAD-containing domains. LÄS MER

  5. 4. Amperometric Carbon Paste Biosensors Based on Horseradish Peroxidase and Oxidases

    Författare :Vijayakumar Rajendran; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Analytical chemistry; on-line monitoring; l-lactate; glucose; ethanol; Biosensor; Carbon paste; Analytisk kemi;

    Sammanfattning : Amperometric carbon paste peroxide sensors based on horseradish peroxidase (HRP) were developed. In the first approach, HRP was chemically modified with polyethylene glycol to improve the stability of the enzyme in the organic paste matrix and compared with native HRP electrode. LÄS MER

  7. 5. Direct electron transfer between cellobiose dehydrogenase and solidmetal or graphite electrodes

    Författare :Ted Larsson; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Physics; Fysik; Physics; Fysik; Physical Chemistry; fysikalisk kemi;

    Sammanfattning : Direct electron transfer (ET) between the enzyme cellobiose dehydrogenase (CDH) and different metal and graphite electrodes has been investigated. The heme domain of the CDH has been shown to play a key-role in the direct ET. A mechanism for the ET between CDH and graphite electrodes was proposed. LÄS MER