Sökning: "non-buttressed"

Hittade 1 avhandling innehållade ordet non-buttressed.

  1. 1. Compounds with Non-Buttressed Metal-Metal Bond between Platinum and Thallium. Model Systems for Photoinduced Two-Electron-Transfer

    Detta är en avhandling från Stockholm : Kemi

    Författare :Mikhail Maliarik; KTH.; [2001]
    Nyckelord :thallium; platinum; cyanide; metal-metal bond; non-buttressed; heterometallic; photoinduced; electron transfer; redox reaction; NMR; chemical shift; spin-spin coupling constant; Raman; EXAFS; X-ray diffraction; equilibrium; oxidation state; oxidative;

    Sammanfattning : A new family of oligonuclear cyano compounds incorporatingtransition (Pt) and main group (Tl) metals bound with anon-buttressed Pt-Tl bond was synthesised in aqueous solution.The metal-metal linkage is formed in the reaction betweenplatinum and thallium in their stable oxidation forms, Pt(II)and Tl(III), orvice versa: Pt(IV) and Tl(I). LÄS MER